Zobrazeno 1 - 10
of 211
pro vyhledávání: '"Koichiro Naemura"'
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 114:157-162
The circular dichroism (CD) and UV spectra of chiral bridged aromatic compounds, 7,8,15,16−tetrahydro-7,15-methanocycloocta[1,2-a:5,6-a′]dinaphthalene-8,16 -diol [(-)-1] and −8,16- dione [(-)-2], have been theoretically calculated by applicatio
Autor:
Shunji Araki, Yoshito Tobe, Keiji Hirose, Naoto Utsumi, Kiyomi Adachi, Koichiro Naemura, Atsushi Nagano, Kazuya Kawabata, Motohiro Sonoda
Publikováno v:
Journal of the American Chemical Society. 124:5350-5364
m-Diethynylbenzene macrocycles (DBMs), buta-1,3-diyne-bridged [4(n)]metacyclophanes, have been synthesized and their self-association behaviors in solution were investigated. Cyclic tetramers, hexamers, and octamers of DBMs having exo-annular octyl,
Publikováno v:
Tetrahedron. 57:8075-8083
Butadiyne-bridged [4 4 ]- and [4 8 ]metacyclophanes having exo -annular t -butyl groups were prepared by intermolecular Eglinton coupling of the dimeric unit or by intramolecular ring closure of the linear tetramer. Comparison of the 1 H and 13 C NMR
Autor:
Jun-ya Kishi, Yoshito Tobe, Koichiro Naemura, Motohiro Sonoda, Tomonari Wakabayashi, Nobuko Nakagawa, Yohji Achiba, Tadamasa Shida
Publikováno v:
Tetrahedron. 57:3629-3636
[16.16.16](1,3,5)Cyclophanes fused by six [4.3.2]propellatriene units, which would serve as precursors to cage polyyne C60H6 and its perchloro derivative C60Cl6, respectively, were prepared. In the negative mode laser desorption mass spectra of the c
Publikováno v:
Organic Letters. 2:3265-3268
Butadiyne-bridged [4(4)](2,6)pyridinophane and [4(6)](2, 6)pyridinophane derivatives were synthesized, and their heteroassociations with the corresponding metacyclophanes and complexations with organic cations were investigated.
Publikováno v:
Tetrahedron: Asymmetry. 11:1199-1210
The enantioselectivity of the kinetic resolution of a primary alcohol which has a chiral center at the β-position of the hydroxyl group was substantially improved by employing a racemic mixture of a chiral acyl donor for enantioselective transesteri
Autor:
Kunihiro Tsumuraya, Motohiro Sonoda, Daisuke Noguchi, Yoshito Tobe, and Yohji Achiba, Toshihiko Fujii, Tomonari Wakabayashi, Nobuko Nakagawa, Koichiro Naemura, Hideki Matsumoto
Publikováno v:
Journal of the American Chemical Society. 122:1762-1775
As a method to generate all-carbon molecules having highly reactive polyyne units from stable precursors, the [2 + 2] cycloreversion of [4.3.2]propella-1,3,11-triene derivatives was developed. To test the efficiency of this method, the reaction was f
Publikováno v:
Scopus-Elsevier
Optically active azophenolic crown ethers having phenyl groups substituted at the respective para-position were prepared and their association constants with chiral aminoethanol derivatives, including 2-amino-2-phenylethanols having an electron-donat
Autor:
Kazuko Ogasahara, Yasushi Nishikawa, Kazuyuki Nishioka, Yoshito Tobe, Keiji Hirose, Koichiro Naemura
Publikováno v:
Tetrahedron: Asymmetry. 9:563-574
Homochiral crown ether ( S , S )- 1 containing 1-naphthyl groups as chiral barriers together with the phenol moiety was prepared by using ( S )- 3 as a chiral subunit which was resolved in enantiomerically pure form by lipase-catalyzed enantioselecti
Autor:
Jun Nishida, Koichiro Naemura, Masami Sawada, Masanori Okamoto, Keiji Hirose, Hitoshi Yamada, Yoshio Takai, Takahiro Kaneda, Toshikazu Tanaka, Ryuichi Arakawa
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :701-710
Chiral recognition of crown ethers toward amino acids and their esters is detected both by electrospray ionization (ESI) and by fast atom bombardment (FAB) mass spectrometry (MS) and then compared as a series of host (H)–guest (G) pairs. A racemic