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pro vyhledávání: '"Kohsuke Yoshitomi"'
Publikováno v:
Synthesis. 44:2365-2373
Acid-catalyzed equilibrium of a mixture of 1,2- and 1,3-methyleneglycerol in 1,4-dioxane affords predominantly the 1,3-isomer via bridged acetal exchange. The minor 1,2-isomer is removed via sequential pivaloylation and tritylation to afford the desi
Autor:
Kohsuke Yoshitomi, Tomoyuki Kawamura, Aki Nakamoto, Hatsuhiko Hattori, Ayato Katagiri, Masaki Kamiya, Hisao Nemoto
Publikováno v:
Chemistry Letters. 39:856-857
A novel method for the preparation of 1,3-bis(2,2-dimethyl-1,3-dioxan-5-yloxy)propan-2-ol, a branched oligoglycerols (BGL), was developed from 1,3-diallylated glycerol in excellent yield.