Frontispiece: Closed Shell Iron(IV) Oxo Complex with an Fe–O Triple Bond: Computational Design, Synthesis, and Reactivity

Autor: Erik Andris, Koen Segers, Jaya Mehara, Lubomír Rulíšek, Jana Roithová

Publikováno v: Angewandte Chemie International Edition. 59

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e4ff29898a48028533b8c4928e7c8b0e
https://doi.org/10.1002/anie.202085162

Closed Shell Iron(IV) Oxo Complex with an Fe-O Triple Bond: Computational Design, Synthesis, and Reactivity

Autor: Jana Roithová, Koen Segers, Jaya Mehara, Lubomír Rulíšek, Erik Andris

Publikováno v: Angewandte Chemie. International Edition, 59, 51, pp. 23137-23144
Angewandte Chemie (International Ed. in English)
Angewandte Chemie. International Edition, 59, 23137-23144

Iron(IV)‐oxo intermediates in nature contain two unpaired electrons in the Fe–O antibonding orbitals, which are thought to contribute to their high reactivity. To challenge this hypothesis, we designed and synthesized closed‐shell singlet iron(

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3b5c8113c5642b4aafd98cf0b35ab506
https://hdl.handle.net/2066/228909