Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Klaus Schloter"'
Autor:
Thomas C. Forschner, Karlheinz Sünkel, Klaus Schloter, Alan R. Cutler, Wolfgang Beck, Günter Urban, Alicia Todaro
Publikováno v:
Inorganic Syntheses
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::31d336614fa0ded857d67e26d8e1366f
https://doi.org/10.1002/9780470132593.ch2
https://doi.org/10.1002/9780470132593.ch2
Autor:
Klaus Schloter, Wolfgang Beck
Publikováno v:
Zeitschrift für Naturforschung B. 35:985-989
Tetrafluoroborate in (η5-C5H5)(OC)3MoFBF3 is easily substituted by cyclic ethers (CH2)nO (n = 2,3,4)at -30°C in CH2Cl2 to give cationic complexes[(η5-C5H5)(OC)3MoO(CH2)n]+BF4-. With dioxane mononuclear and dinuclear dioxane bridged cationic comple
Autor:
Klaus Schloter, Robert Weiss
Publikováno v:
Tetrahedron Letters. 16:3491-3494
Publikováno v:
Journal of Organometallic Chemistry. 322:77-88
The complexes (η 5 -C 5 H 5 )(OC) 3 MX (M Mo, W; X OSO 2 F, OSO 2 CF 3 , OSO 2 C 6 F 13 , OC(O)C 3 F 7 ), (OC) 5 MX (M Mn, Re; X OSO 2 C 6 F 13 , OC(O) 3 F 7 , OC(O)C 7 F 15 ) are obtained from their alkyl complexes and the correspon
Publikováno v:
Chemische Berichte. 113:3775-3782
(η5-C5H5)(OC)3MoBF4 setzt sich mit Wasserdampf bei 20°C zum Aquakomplex [(η5-C5H5)(OC)3-Mo(OH2)]+BF4− (1) um. Der Aqualigand in 1 bildet in festem Zustand Wasserstoffbrucken zum BF4−-Anion aus. Mit uberschussigem Wasser entsteht aus 1 ein Hydr
Publikováno v:
Journal of Organometallic Chemistry. 241:333-342
The highly reactive complexes (π-C 5 H 5 )(CO) 3 MoX (X = FBF 3 , FSbF 5 ) react with (π-C 5 H 5 )(CO) 3 MoCH 3 , (π-C 5 H 5 )(CO) 2 FeCH 3 or (π-C 5 H 5 )(CO) 2 FeCOCH 3 and cis, trans -Ph 3 P(CO) 4 MnCH 3 to give [(π-C 5 H 5 )(CO) 2 Mo(μ 2 -
Publikováno v:
Journal of Organometallic Chemistry. 214:81-86
(OC) 5 ReFBF 3 (I) is obtained by abstraction of H - or CH 3 - from (OC) 5 ReH or (OC) 5 ReCH 3 , respectively, using Ph 3 CBF 4 . Treatment of I with water vapour yields the trifluorohydroxoborato complex (OC) 5 ReOHBF 3 (III). The reaction of I wit
Autor:
Wolfgang Beck, Klaus Schloter
Publikováno v:
Zeitschrift für Naturforschung B. 33:1214-1222
Hydride abstraction from the hydrides (π-C5H5)(OC)3MH (M = Mo, W) using Ph3C+X_ (X = BF4, PF6) affords the compounds (π-C5H5)(OC)3MX in high yields. IR data indicate that in these complexes tetrafluoroborate and hexafluorophosphate are coordinated