Výsledky vyhledávání - "Kiyokazu Santo"

Iron carbonyl complexes of N,C,S-pincer ligands with a pendant thioether arm: Synthesis, structures and reactivity

Autor: Masakazu Hirotsu, Yui Tanaka, Isamu Kinoshita, Kiyokazu Santo

Publikováno v: Polyhedron. 143:201-208

Thiolate-bridged diiron carbonyl complexes of N,C,S-pincer ligands with a pendant thioether arm were synthesized by treatment of [Fe(CO)5] with Schiff bases, which were derived from 4-formyldibenzothiophene and 2-(methylthio or phenylthio)aniline. Cl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bd9ac7acd7f9881d367ebf4187dfb1f2
https://doi.org/10.1016/j.poly.2017.10.014

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Diiron Carbonyl Complexes Bearing an N,C,S-Pincer Ligand: Reactivity toward Phosphines, Heterolytic Fe–Fe Cleavage, and Electrocatalytic Proton Reduction

Autor: Masakazu Hirotsu, Chiaki Tsuboi, Isamu Kinoshita, Kiyokazu Santo

Publikováno v: Organometallics. 33:4260-4268

The thiolate-bridged diiron carbonyl complex [{Fe(μ-PyBPT-κ3N,C,S)(CO)2}Fe(CO)3] (1) consists of two units, Fe(PyBPT)(CO)2 and Fe(CO)3, where the N,C,S-pincer ligand PyBPT is a doubly deprotonated form of 3′-(2″-pyridyl)-1,1′-biphenyl-2-thiol

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8adb7ad9dbd847c1dd64da3816227a02
https://doi.org/10.1021/om500558h

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Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C–S Bond Cleavage and CO Insertion

Autor: Masakazu Hirotsu, Isamu Kinoshita, Takanori Nishioka, Kiyokazu Santo, Keisuke Kawamoto

Publikováno v: Bulletin of the Chemical Society of Japan. 88:613-615

Ruthenium complexes containing an N,N,C,S-metalloligand or an N,N,C,O-organoligand with a sulfido carbonyl Ru cluster were obtained by the reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [R...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::84a19d73b266986127f39497cbb2ca87
https://doi.org/10.1246/bcsj.20140379

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Carbon- and Sulfur-Bridged Diiron Carbonyl Complexes Containing N,C,S-Tridentate Ligands Derived from Functionalized Dibenzothiophenes: Mimics of the [FeFe]-Hydrogenase Active Site

Autor: Masakazu Hirotsu, Kiyokazu Santo, Isamu Kinoshita, Hideki Hashimoto

Publikováno v: Organometallics. 31:7548-7557

Photochemical reactions of [Fe(CO)5] with dibenzothiophene (DBT) derivatives bearing a N-donor group produced a series of C,S-bridged diiron carbonyl complexes [{Fe(μ-L′-κ3N,C,S)(CO)2}Fe(CO)3], as previously reported for 4-(2′-pyridyl)dibenzoth

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::97e7fc7a2c53763bf2cee06a4981c620
https://doi.org/10.1021/om300826y

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Formation, reactivity and redox properties of carbon- and sulfur-bridged diiron complexes derived from dibenzothienyl Schiff bases: effect of N,N- and N,P-chelating moieties

Autor: Kiyokazu Santo, Isamu Kinoshita, Masakazu Hirotsu

Publikováno v: Dalton transactions (Cambridge, England : 2003). 44(9)

Dibenzothienyl Schiff bases, DBT-NN and DBT-NP, were derived from condensation of 4-formyldibenzothiophene with N,N-dimethylethylenediamine and 2-(diphenylphosphino)ethylamine, respectively. A photochemical reaction of [Fe(CO)5] with DBT-NN produced

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d28df9e820c2f431e47d112ea7127392
https://pubmed.ncbi.nlm.nih.gov/25623444

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