Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Kirsty A. Macpherson"'
Autor:
David A. V. Morton, A. Guy Orpen, Selby A. R. Knox, Graeme Hogarth, Brian R. Lloyd, Kirsty A. Macpherson
Publikováno v:
Inorganica Chimica Acta. 251:167-176
In toluene at 100°C the dimetallacyclopentenone complex [Fe2(CO)5{μ-σ:η3-C(O)CHCH}(μ-dppm)] (1a) isomerises to the μ-vinyl complex [Fe2(CO)6{μ-C(CH2)P(Ph2)CH2PPh2}] (2) via intramolecular nucleophilic attack of phosphorus on a carbon of the me
Autor:
Frauke Melchior, Kirsty A. Macpherson, David A. V. Morton, Graeme Hogarth, A. Guy Orpen, Selby A. R. Knox, Nancy M. Doherty
Publikováno v:
Inorganica Chimica Acta. :257-270
Upon heating in toluene at reflux the di-iron heptacarbonyl complexes [Fe2(CO)6(μ-CO)(μ-R2PCH2PR2)] (RPh, Me, Et, iPr, OEt) lose carbon monoxide, resulting in phosphorus-methylene bond cleavage to give the μ- phosphidomethyl complexes [Fe2(CO)6
Autor:
Robert Edgar Colborn, Selby A. R. Knox, Kirsty A. Macpherson, Kevin A. Mead, A. Guy Orpen, Andrew F. Dyke, Benjamin P. Gracey
Publikováno v:
J. Chem. Soc., Dalton Trans.. :761-771
Ultraviolet irradiation of the metallacycle [Ru2(CO)(μ-CO){μ-C(O)C2Ph2}(η-C5H5)2] (1) in tetrahydrofuran (thf) gives the complex [Ru2(μ-CO)(μ-C2Ph2)(η-C5H5)2] (2), shown by X-ray diffraction to have a ruthenium–ruthenium double bond [RuRu 2.5
Autor:
Andrew F. Dyke, Kirsty A. Macpherson, B. P. Gracey, Kevin A. Mead, Robert Edgar Colborn, Selby A. R. Knox, A. G. Orpen
Publikováno v:
ChemInform. 21
The air-stable title complex (II) (space group Pbca, Z = 8) is obtained on UV irradiation of the metallacycle (I).
Autor:
A. G. Orpen, Robert Edgar Colborn, Peter Woodward, Kirsty A. Macpherson, J. Roue, Kevin A. Mead, Andrew F. Dyke, Selby A. R. Knox
Publikováno v:
Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences. 308:67-73
The Fischer-Tropsch synthesis of hydrocarbons probably involves an array of carbon-carbon bond-formation processes occurring to unite carbene, carbyne, alkyl, olefin, and related species on a metal surface. In seeking to understand the nature of such
Publikováno v:
Polyhedron. 7:837-845
Photolysis of [Ru2(CO)4(η-C5R52] (R = H or Me) in the presence of allene yields complexes [(η-C5R5)(CO)2RuCH 2C(CH2)C(CH2)CH2Ru(CO)2(η-C5R5)] and [Ru2(CO)2{(μ-C(Me)CHCH2CCH2)}(η-C5Me5)2], containing dimers of allene derived by C(2)C(2) and C(
Publikováno v:
Journal of Organometallic Chemistry. 272:C45-C48
The dynamic behaviour (cis/trans isomerisation via CO migration) of [FeRu(CO)2 (μ-CO)2 (η-C5H5)2] in solution, the determination of the molecular structure of trans-[FeRu(CO)2(μ-CO)2(η-C5H5)2] by X-ray diffraction, and the developing organic chem
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1935-1944
The iron–ruthenium complex [FeRu(CO)4(η-C5H5)2] is obtained in 60% yield from the reaction of Na[Fe(CO)2(η-C5H5)] with [RuI(CO)2(η-C5H5)]. In the solid state a trans-[FeRu(CO)2(µ-CO)2(η-C5H5)2] structure has been established by X-ray diffracti
Autor:
Michael J. Zaworotko, Kirsty A. Macpherson, Selby A. R. Knox, Gordon W. Bushnell, Stephen R. Stobart, D. O. Kimberley Fjeldsted
Publikováno v:
Organometallics. 4:1107-1114
Publikováno v:
Journal of Organometallic Chemistry. 239:C15-C18
The metalmetal double-bonded μ-alkyne complex [Ru2(μ-CO)(μ-C2Ph2) (η-C5H5)2] (1) reacts with diazomethane at 0°C to yield Ru2(CO)(η-CH2) {μ-C(Ph)C(Ph)CH2} (η-C5H5)2] (2) incorporating two methylene units, one bridging the metal atoms and o