Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Kiron Kumar Ghosh"'
Publikováno v:
Angewandte Chemie. 132:23327-23331
Publikováno v:
Angewandte Chemie International Edition. 59:23127-23131
In this study we report the identification of a novel class of ligands for palladium-catalyzed C(sp3 )-H activation that enables the direct alkynylation of free carboxylic acid substrates. In contrast to previous synthetic methods, no introduction/re
Autor:
Manuel van Gemmeren, Alexander Uttry, Francesca Ghiringhelli, Arup Mondal, Philipp Wedi, Kiron Kumar Ghosh
Publikováno v:
Angewandte Chemie. 132:12948-12952
Publikováno v:
Organic Letters. 21:7154-7157
The controlled construction of defined oxidation patterns is one of the key aspects in the synthesis of natural products and bioactive molecules. Towards this goal, we herein report a novel protocol for the Pd-catalyzed direct β-C(sp3)-H acetoxylati
Publikováno v:
Angewandte Chemie (International Ed. in English)
In this study we report the identification of a novel class of ligands for palladium‐catalyzed C(sp3)−H activation that enables the direct alkynylation of free carboxylic acid substrates. In contrast to previous synthetic methods, no introduction
We report the ligand enabled C(sp3)–H activation/olefination of free carboxylic acids in the γ-position. Through an intramolecular Michael-addition, δ-lactones are obtained as products. Two distinct ligand classes are identified that enable the c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::342b82613d0462b5984ca80ad1debebf
https://doi.org/10.26434/chemrxiv.11857857
https://doi.org/10.26434/chemrxiv.11857857
Autor:
Francesca Ghiringhelli, Kiron Kumar Ghosh, Alexander Uttry, Arup Mondal, Philipp Wedi, Manuel van Gemmeren
Publikováno v:
Angewandte Chemie (International Ed. in English)
We report the ligand‐enabled C−H activation/olefination of free carboxylic acids in the γ‐position. Through an intramolecular Michael addition, δ‐lactones are obtained as products. Two distinct ligand classes are identified that enable the
Autor:
Kiron Kumar Ghosh, Manuel van Gemmeren
Publikováno v:
Chemistry - A European Journal. 23:17697-17700
A generally applicable Pd-catalyzed protocol for the β-C(sp3 )-H arylation of propionic acid and related α-branched aliphatic acids is reported. Enabled by the use of N-acetyl-β-alanine as ligand our protocol delivers a broad range of arylation pr