Zobrazeno 1 - 10
of 30
pro vyhledávání: '"Kirby V. Scherer"'
Autor:
Philip Bruce Henderson, Hiroko Saida, Eiji Hayashi, Kirby V. Scherer, Richard Edward Fernandez, Takashi Abe, Haruhiko Fukaya, Taizo Ono
Publikováno v:
Journal of Fluorine Chemistry. 97:173-182
The reactivity of persistent perfluoroalkyl radical, perfluoro-3-ethyl-2,4-dimethyl-3-pentyl ( 1 ), with various electron-donating reagents was investigated. It is revealed that 1 which is robust under oxidative conditions is rather vulnerable under
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::40017a00d87a58ced15398fa97a7f930
https://doi.org/10.1016/s0022-1139(99)00046-9
https://doi.org/10.1016/s0022-1139(99)00046-9
Publikováno v:
Journal of Fluorine Chemistry. 75:197-204
Liquid-phase photofluorination (LPPF) of 2-phenyl-2-methoxyhexafluoropropane 1 gave the desired F -2-cyclohexyl-2-methoxypropane, 2 , in 21% yield. An unusual rearranged product, F -2-cyclohexylmethyl isopropyl ether, 4 , and a degradation product, F
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b7d109b888f9b99a26edda4d58a6bcb9
https://doi.org/10.1016/0022-1139(95)03325-2
https://doi.org/10.1016/0022-1139(95)03325-2
Publikováno v:
Journal of Fluorine Chemistry. 73:267-272
The tertiary amines derived from hexafluoropropene dimers were subjected to liquid-phase photofluorination (LPPF). The corresponding perfluorotertiary amines, which were difficult to synthesize by the conventional fluorination methods such as electro
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::863f81b5efc9276f878e90297a75dbcf
https://doi.org/10.1016/0022-1139(95)03229-7
https://doi.org/10.1016/0022-1139(95)03229-7
Autor:
Kirby V. Scherer, Elizabeth Forrester Mccord, Brian C. Auman, William H. Shaw, David Page Higley
Publikováno v:
Polymer. 36:651-656
The preparation of a new perfluoroalkylated diamine, 5-[1H,1H-2-bis(trifluoromethyl)heptafluoropentyl]-1,3-phenylenediamine, is described. Poly(amic acid)s and polyimides were prepared from this new diamine and polyimides were evaluated as films for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::576387177fdb92ee90482ad48058bd83
https://doi.org/10.1016/0032-3861(95)91576-s
https://doi.org/10.1016/0032-3861(95)91576-s
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 31:2039-2056
Theoretical calculations of miscibility windows for binary polymer blends in which one component is an essentially alternating copolymer of tetrafluoroethylene and vinyl alcohol (FVOH) are reported. FVOH has an inherently low solubility parameter [
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5bc770036127f42b4c38a575af990ef2
https://doi.org/10.1002/pola.1993.080310811
https://doi.org/10.1002/pola.1993.080310811
Publikováno v:
Journal of Fluorine Chemistry. 50:47-65
This paper describes a novel, safe, effective technique, with a new reactor design, for the synthesis of perfluorochemicals. This method, the liquid-phase photofluorination with undiluted fluorine, is applicable to the preparative-scale synthesis of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::45c285ac363d0b2375d4eea00b8db8d5
https://doi.org/10.1016/s0022-1139(00)82178-8
https://doi.org/10.1016/s0022-1139(00)82178-8
Publikováno v:
Chemical Research in Toxicology. 3:2-7
Electron spin resonance (ESR) analysis at room temperature of the particles produced during the aerobic pyrolysis of perfluoro polymers (PFP) shows the presence of end-chain peroxyl radicals. These radicals, which would normally have lifetimes of sev
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::452eab0b0bd19034332cf66350eafc2f
https://doi.org/10.1021/tx00013a001
https://doi.org/10.1021/tx00013a001
Autor:
William C. Seidel, William A. Pryor, Allan H. Olson, Kirby V. Scherer, Shamala K. Nuggehalli, Joanne K. Bonesteel, Daniel F. Church, Dwain Cline
Publikováno v:
Chemical research in toxicology. 4(2)
Submicrometer solid-particle (fume) aerosols with up to about 10(8) particles/cm3 are formed when dilute vapors of low molecular weight (MW) (ca. 5000-10,000) perfluoro polymers condense in air. The aerosol (e.g., 0.2 mg/m3) formed from these vapors
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c792154bfc7ac75d65ce3a7d45cd231b
https://pubmed.ncbi.nlm.nih.gov/1664259
https://pubmed.ncbi.nlm.nih.gov/1664259
Autor:
Thomas M. Lachocki, Shamala K. Nuggehalli, Daniel F. Church, William A. Pryor, Kirby V. Scherer
Publikováno v:
Chemical Research in Toxicology. 2:174-180
Spin adducts are observed when the unfiltered smoke produced during the aerobic pyrolysis of perfluoro polymers (PFP) is bubbled through a solution of the ESR spin trap alpha-phenyl-N-tert-butylnitrone (PBN). The spin adducts include those from an ox
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c1804a2fb3b64847ecd3dfcaa58ca72d
https://doi.org/10.1021/tx00009a009
https://doi.org/10.1021/tx00009a009
Publikováno v:
Tetrahedron Letters. 6:1199-1205
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a517d21b0b7234d5dac0ff1708fb2441
https://doi.org/10.1016/s0040-4039(01)83996-4
https://doi.org/10.1016/s0040-4039(01)83996-4