Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Kim M. Touchette"'
Autor:
Kim M. Touchette, Hilton M. Weiss
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1523-1528
The addition of 0.1 M quaternary ammonium bromide to a solution of 20% trifluoroacetic acid in methylene chloride causes a large rate increase in the reaction of non-conjugated alkynes. The initial vinyl bromide product reacts further to provide a mi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::36e5828b23a7b41b135d58557befc573
https://doi.org/10.1039/a703569a
https://doi.org/10.1039/a703569a
Autor:
Hilton M. Weiss, Kim M. Touchette
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1517-1522
The addition of 0.1 M quaternary ammonium halide to a solution of 20% trifluoroacetic acid in methylene chloride causes a large rate increase in the reaction of simple alkenes leading to a mixture of alkyl halides and trifluoroacetates. The mechanism
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::14f4911cc98b495febb68ac4cf53000e
https://doi.org/10.1039/a703570e
https://doi.org/10.1039/a703570e
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :756-758
The reaction of oct-4-yne with 20% trifluoroacetic acid and a variety of relatively weak nucleophiles in methylene chloride was found to produce a mixture of anion incorporated and solvent incorporated products. The rates of these reactions with a ra
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cfebaf00cefeee6fbecb06a7f9156b74
https://doi.org/10.1039/b111724f
https://doi.org/10.1039/b111724f
Autor:
Kim M. Touchette, Hilton M. Weiss
Publikováno v:
ChemInform. 29
The addition of 0.1 M quaternary ammonium bromide to a solution of 20% trifluoroacetic acid in methylene chloride causes a large rate increase in the reaction of non-conjugated alkynes. The initial vinyl bromide product reacts further to provide a mi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4b46572ad23c533e3d011ea0e16dc421
https://doi.org/10.1002/chin.199836093
https://doi.org/10.1002/chin.199836093
Publikováno v:
The Journal of Organic Chemistry. 57:6305-6313
Furano alcohol 5, the key intermediate in our proposed synthesis of the guaianolide sesquiterpene geigerin (1), was prepared by a novel sequence of reactions which includes a chemoselective oxy-Cope transformation of enynols of general structure 42.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c8f1b42b3b8b27acb2755ae233b1bd00
https://doi.org/10.1021/jo00049a044
https://doi.org/10.1021/jo00049a044
Publikováno v:
Organicbiomolecular chemistry. 1(12)
In a weakly acidic solution, the addition of HBr to 1-phenylprop-1-yne produces predominantly the anti-Markovnikov product. In this paper, we consider five possible explanations for this behavior and conclude that the concerted addition is occurring
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::c753b0c5617b5a0aa206aab64d928450
https://pubmed.ncbi.nlm.nih.gov/12945906
https://pubmed.ncbi.nlm.nih.gov/12945906
Autor:
Kim M. Touchette
Publikováno v:
Journal of Chemical Education. 83:929
The synthesis of N-(2-hydroxy-3-methoxybenzyl)-N-p-tolylacetamide is a fast, simple three-step sequence that serves as a useful example of the reductive amination reaction for the organic chemistry laboratory. The first step is a spectacular solvent-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b41bbe0e115fef027debad1140453b9c
https://doi.org/10.1021/ed083p929
https://doi.org/10.1021/ed083p929
Publikováno v:
Organic & Biomolecular Chemistry. 1:2148
The reaction of aryl alkynes with dilute methylene chloride solutions of quaternary ammonium bromide and 20% trifluoroacetic acid produces primarily the syn Markovnikov adducts of hydrogen bromide. At moderate concentrations of the bromide, the princ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c6df045c8148e0183848ca2cbb48008
https://doi.org/10.1039/b300042g
https://doi.org/10.1039/b300042g
Publikováno v:
Organic & Biomolecular Chemistry. 1:2152
In a weakly acidic solution, the addition of HBr to 1-phenylprop-1-yne produces predominantly the anti-Markovnikov product. In this paper, we consider five possible explanations for this behavior and conclude that the concerted addition is occurring
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::42942e881ff0dab645899200caf602d1
https://doi.org/10.1039/b300045a
https://doi.org/10.1039/b300045a
Publikováno v:
Journal of Chemical Education. 71:534
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::badcb41bc37e443435151f91a19c8964
https://doi.org/10.1021/ed071p534
https://doi.org/10.1021/ed071p534