Výsledky vyhledávání

Cleavage of homometallic and formation of heterometallic M–M bonds. Serendipitous syntheses of bimetallic MnPd(µ-PPh2)(CO)4(η2-P–P) (P–P = dppm, dppe, dppf) and polymetallic Mn2Pd2Ag(µ-Cl)(µ-PPh2)2(µ-dppm)(CO)8

Autor: Ye Liu, Jagadese J. Vittal, Tzi Sum Andy Hor, Kim Hun Lee

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :2747-2751

Condensation of [Mn2(CO)8(μ-PPh2)]− with Pd(II) assisted by Ag(I) leads to cluster disproportionation, viz. Mn2Pd2Ag(μ-Cl)(μ-PPh2)2(μ-dppm)(CO)8 and MnPd(μ-PPh2)(CO)4(η2-P–P) (P–P = dppm, dppe, dppf). The former shows a distorted bow-tie

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e4d6cffca1b036c1f19f7c457e94c0d0
https://doi.org/10.1039/b202001g

Zobrazit plný text záznamu

Diphosphine as an Overhead Bridge across a Heterometallic M−M‘ Bond. A Flexible Cluster System in (P−P)AuMn2(CO)7(μ-PPh2) that Accommodates All Common Diphosphines

Autor: and Pauline M. N. Low, Yuh-Sheng Wen and, Kim Hun Lee, T. S. Andy Hor, Ling-Kang Liu

Publikováno v: Organometallics. 20:3250-3254

The inter-triangular diphosphine bridge in [AuMn2(CO)8(μ-PPh2)]2(μ-P−P) turns into an intra-triangular one as it undergoes amine-oxide-promoted decarbonylation to give (P−P)AuMn2(CO)7(μ-PPh2) (P−P ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b1bcf635b3605fd783d91ef1ad556f8b
https://doi.org/10.1021/om0100434

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání