Observation of Rare Tri6Di9 Imine Cages Using Highly Fluorinated Building Blocks

Autor: Tom Fleck-Kunde, Emma H. Wolpert, LauraHorst zur zur, Robert Oestreich, Christoph Janiak, Kim E. Jelfs, Bernd M. Schmidt

Publikováno v: Organic Materials, Vol 4, Iss 04, Pp 255-260 (2022)

Abstract The first synthesis of organic Tri 6 Di 9 cages is presented. Two structurally distinct Tri 6 Di 9 cages were synthesised by combining a highly fluorinated aldehyde with two ditopic amines. Although the pure compounds could not be iso

Externí odkaz: https://doaj.org/article/6ff762f8f07848adae4951831cad38a9

Multivariate analysis of disorder in metal–organic frameworks

Autor: Adam F. Sapnik, Irene Bechis, Alice M. Bumstead, Timothy Johnson, Philip A. Chater, David A. Keen, Kim E. Jelfs, Thomas D. Bennett

Publikováno v: Nature Communications, Vol 13, Iss 1, Pp 1-13 (2022)

Structural disorder in materials is challenging to characterise. Here, the authors use multivariate analysis of atomic pair distribution functions to study structural collapse and melting of metal–organic frameworks, revealing powerful mechanistic

Externí odkaz: https://doaj.org/article/85ffc094b2784171ad43e1f019862885

Mixed hierarchical local structure in a disordered metal–organic framework

Autor: Adam F. Sapnik, Irene Bechis, Sean M. Collins, Duncan N. Johnstone, Giorgio Divitini, Andrew J. Smith, Philip A. Chater, Matthew A. Addicoat, Timothy Johnson, David A. Keen, Kim E. Jelfs, Thomas D. Bennett

Publikováno v: Nature Communications, Vol 12, Iss 1, Pp 1-12 (2021)

The structures of amorphous MOFs are challenging to characterise. Here the authors use electron microscopy and pair distribution function methods, coupled with a polymerisation-based algorithm to determine the atomic structure of Fe-BTC, demonstratin

Externí odkaz: https://doaj.org/article/54151337285c432a92704f51dfb2d1df

Thin Film Composite Membranes with Regulated Crossover and Water Migration for Long‐Life Aqueous Redox Flow Batteries

Autor: Rui Tan, Anqi Wang, Chunchun Ye, Jiaxi Li, Dezhi Liu, Barbara Primera Darwich, Luke Petit, Zhiyu Fan, Toby Wong, Alberto Alvarez‐Fernandez, Mate Furedi, Stefan Guldin, Charlotte E. Breakwell, Peter A. A. Klusener, Anthony R. Kucernak, Kim E. Jelfs, Neil B. McKeown, Qilei Song

Publikováno v: Tan, R, Wang, A, Ye, C, Li, J, Liu, D, Darwich, B P, Petit, L, Fan, Z, Wong, T, Alvarez-Fernandez, A, Furedi, M, Guldin, S, Breakwell, C E, Klusener, P A A, Kucernak, A R, Jelfs, K E, McKeown, N B & Song, Q 2023, ' Thin Film Composite Membranes with Regulated Crossover and Water Migration for Long-Life Aqueous Redox Flow Batteries ', Advanced Science . https://doi.org/10.1002/advs.202206888
e2206888

Redox flow batteries (RFBs) are promising for large-scale long-duration energy storage owing to their inherent safety, decoupled power and energy, high efficiency, and longevity. Membranes constitute an important component that affects mass transport

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::719a3ceb1dd479763be7b0ba3de7e5fb
https://doi.org/10.1002/advs.202206888

Ion-selective microporous polymer membranes with hydrogen-bond and salt-bridge networks for aqueous organic redox flow batteries

Autor: Anqi Wang, Rui Tan, Dezhi Liu, Jiaxin Lu, Xiaochu Wei, Alberto Alvarez‐Fernandez, Chunchun Ye, Charlotte Breakwell, Stefan Guldin, Anthony R. Kucernak, Kim E. Jelfs, Nigel P. Brandon, Neil B. McKeown, Qilei Song

Publikováno v: Wang, A, Tan, R, Liu, D, Lu, J, Wei, X, Alvarez-Fernandez, A, Ye, C, Breakwell, C, Guldin, S, Kucernak, A R, Jelfs, K E, Brandon, N P, McKeown, N B & Song, Q 2023, ' Ion-Selective Microporous Polymer Membranes with Hydrogen-Bond and Salt-Bridge Networks for Aqueous Organic Redox Flow Batteries ', Advanced Materials, vol. 35, no. 12, 2210098 . https://doi.org/10.1002/adma.202210098

Redox flow batteries (RFBs) have great potential for long-duration grid-scale energy storage. Ion conducting membranes are a crucial component in RFBs, allowing charge-carrying ions to transport while preventing the cross-mixing of redox couples. Com

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::58e03b775eab3a2771f2f65248d7f8be
http://hdl.handle.net/10044/1/102073