Chemoselective formation of cyclo-aliphatic and cyclo-olefinic 1,3-diols via pressure hydrogenation of potentially biobased platform molecules using Knölker-type catalysts

Autor: Darya Hadavi, Christian A. M. R. van Slagmaat, Khi Chhay Chou, Alfonso J. Schwalb Freire, Stefaan M. A. De Wildeman, Paul L. Alsters, Peiliang Han, Gerard K. M. Verzijl, Teresa Faber, Peter J. L. M. Quaedflieg

Publikováno v: Dalton Transactions, 50(29), 10102-10112. Royal Society of Chemistry

The hydrogenative conversions of the biobased platform molecules 4-hydroxycyclopent-2-enone and cyclopentane-1,3-dione to their corresponding 1,3-diols are established using a pre-activated Knolker-type iron catalyst. The catalyst exhibits a high sel

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7925c73e4dcd0911b1a502b70d9f1cde
https://doi.org/10.1039/d1dt01252e

Synthesis and Catalytic Application of Knölker-Type Iron Complexes with a Novel Asymmetric Cyclopentadienone Ligand Design

Autor: Darya Hadavi, Khi Chhay Chou, Lukas Morick, Burgert Blom, Christian A. M. R. van Slagmaat, Stefaan M. A. De Wildeman

Publikováno v: Catalysts
Volume 9
Issue 10
Catalysts, Vol 9, Iss 10, p 790 (2019)
Catalysts, 9(10):790. Multidisciplinary Digital Publishing Institute (MDPI)

Asymmetric catalysis is an essential tool in modern chemistry, but increasing environmental concerns demand the development of new catalysts based on cheap, abundant, and less toxic iron. As a result, Knö
lker-type catalysts have emerged as

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::464695bb9c4c8599a10a16154eefe01a
https://doi.org/10.3390/catal9100790