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Electrocatalytic Proton Reduction by a Cobalt(III) Hydride Complex with Phosphinopyridine PN Ligands
Autor:
Stuart A. Cavill, Adrian C. Whitwood, Robin N. Perutz, Richard E. Douthwaite, Khanittha Walaijai
Publikováno v:
Inorganic chemistry. 59(24)
Cobalt complexes with 2-(diisopropylphosphinomethyl)pyridine (PN) ligands have been synthesized with the aim of demonstrating electrocatalytic proton reduction to dihydrogen with a well-defined hydride complex of an Earth-abundant metal. Reactions of