Zobrazeno 1 - 10
of 39
pro vyhledávání: '"Khalil J. Asali"'
Publikováno v:
Transition Metal Chemistry. 43:549-554
Reactions of [(η3-C3H5)Mo(CO)2(X)(py)2] (X = Cl (1), Br (2); py = pyridine) with 1,2-bis(diphenylphosphino)ethane (= dppe) in toluene solution resulted in replacement of the py ligands and the formation of [(η3-C3H5)Mo(CO)2(X)(κ2-P,Pʹ-dppe)]. The
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2eea88f7a02767e57da49da13d9b8930
https://doi.org/10.1007/s11243-018-0238-0
https://doi.org/10.1007/s11243-018-0238-0
Publikováno v:
Journal of Coordination Chemistry. 70:3810-3822
Group 6 metal carbonyls [cis-M(CO)4(amine)(EPh3)] (M = Mo, W; amine = piperidine (pip), pyridine (py); E = As, Sb) have been prepared and characterized. These complexes react thermally in chlorobenzene solutions with phosphine or phosphite ligands (=
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fceb96642491e33f5fb0c1cc548d0942
https://doi.org/10.1080/00958972.2017.1402117
https://doi.org/10.1080/00958972.2017.1402117
Publikováno v:
Dalton Transactions. 46:2937-2947
The synthetic models of the active site of an [FeFe]-hydrogenase containing a Sn atom in the bridgehead of the diselenato ligand, namely [Fe2(CO)6{μ-(SeCH2Se)SnMe2}], 3 and [Fe2(CO)6{μ-(SeCH2)2SnMe2}], 4 have been synthesized and characterized by d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fba73361fe4623888b21e2e14f2a70f8
https://doi.org/10.1039/c7dt00057j
https://doi.org/10.1039/c7dt00057j
Publikováno v:
Transition Metal Chemistry. 40:471-475
The bimetallic complexes (μ-2,6-dap)[M(CO)5]2 [2,6-dap = 2,6-diaminopyridine, M = Cr (1), Mo (2), W (3)] were synthesized from M(CO)6 and 2,6-diaminopyridine. The complexes were characterized on the basis of their carbonyl stretching frequencies and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dbd2287a61186fe911e1c02e800210e0
https://doi.org/10.1007/s11243-015-9936-z
https://doi.org/10.1007/s11243-015-9936-z
Publikováno v:
Transition Metal Chemistry. 40:131-135
Treatment of the intermediate M(CO)5(THF) with 4,4′-bipyridine produced the bimetallic complexes (μ-bpy)[M(CO)5]2 (M = Cr (1), Mo (2), W (3); bpy = 4,4′-bipyridine). These complexes were characterized on the basis of their carbonyl stretching fr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5c15dcff287f9c15da9a61e9de020f3f
https://doi.org/10.1007/s11243-014-9898-6
https://doi.org/10.1007/s11243-014-9898-6
Autor:
Mohammad El-khateeb, Heinrich Lang, Firas F. Awwadi, Mousa Al-Noaimi, Marcus Korb, Enas Al-Rabaee, Khalil J. Asali, Deeb Taher
Publikováno v:
Inorganica Chimica Acta. 421:553-558
Various new thio- and selenosulfonato complexes of iron were synthesized by straight forward route. Treatment of the iron chalcogenides, (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se; x = 1) with sulfonyl chlorides produced the corresponding thio- or
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3c8688adc36ffde86b9ec22a76fc513d
https://doi.org/10.1016/j.ica.2014.07.021
https://doi.org/10.1016/j.ica.2014.07.021
Autor:
Naim H. Al-Said, Khalil J. Asali
Publikováno v:
Jordan Journal of Chemistry. 8:57-62
new series of dinuclear group 6 metal tetracarbonyl complexes containing two bis(phenylthio)alkane ligands symmetrically bridging two M(CO)4 moieties of the type cis-{[M(CO)4]2(?-PhS(CH2)nSPh)2} [M = W (1), Mo (2); n = 3 (a), 4 (b), 5 (c), 6 (d)] hav
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b63d84d35dc6cdd5d5c7dcdb41ef4f12
https://doi.org/10.12816/0001516
https://doi.org/10.12816/0001516
Publikováno v:
Polyhedron. 38:185-189
The hydrosulfido complexes CpM(CO)3SH (M = Mo, W) react with one equivalent of O-alkyl oxalyl chlorides, RO2CCOCl, to form the corresponding O-alkylthiooxalato complexes CpM(CO)3SCOCO2R [M = Mo (1), W (2); R = Me (a), Et (b)]. The reaction of the hyd
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0f520049ad7ba263e0e0c539fcd79d5e
https://doi.org/10.1016/j.poly.2012.03.013
https://doi.org/10.1016/j.poly.2012.03.013
Autor:
Khalil J. Asali
Publikováno v:
Advanced Materials Research. :13-16
Reactions of the labile complex (Me3tach)M(CO)3 (Me3tach = 1,3,5-trimethyl-1,3,5-triazacyclohexane; M = W, Mo) with bis(phenylthio)alkanes ( = PhS(CH2)nSPh), (2:3 molar ratio) in CH2Cl2 as solvent (at 35 oC M = W, 0 oC M = Mo) afforded in good yields
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dfe68d1a21e6eb7fdde4909181568b6f
https://doi.org/10.4028/www.scientific.net/amr.93-94.13
https://doi.org/10.4028/www.scientific.net/amr.93-94.13
Autor:
Helmar Görls, Anas Abuseni, Mohammad El-khateeb, Wolfgang Weigand, Khalil J. Asali, Ibrahim Jibril
Publikováno v:
Transition Metal Chemistry. 34:419-424
A controlled substitution reaction of the chlorine atoms of 1,3,5-benzenetricarbonyl trichloride by the organoiron fragment (CpFe(CO)2S) has been achieved. The complexes CpFe(CO)2SCO-3,5-C6H3(COCl)2 (1), 1,3-[CpFe(CO)2SCO]2-5-C6H3COCl (2) and 1,3,5-[
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9b3d84ea52706c638e95290166b63bea
https://doi.org/10.1007/s11243-009-9211-2
https://doi.org/10.1007/s11243-009-9211-2