Functionalization of 3-Iodo-N,N-Diisopropylferrocene-Carboxamide, a Pivotal Substrate to Open the Chemical Space to 1,3-Disubstituted Ferrocenes

Autor: William Erb, Palakodety Radha Krishna, Khadega Al-Mekhlafi, Florence Mongin, Vincent Dorcet, Thierry Roisnel, Lingaswamy Kadari

Publikováno v: Advanced Synthesis and Catalysis
Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2020, 362 (4), pp.832-850. ⟨10.1002/adsc.201901393⟩
Advanced Synthesis and Catalysis, 2020, 362 (4), pp.832-850. ⟨10.1002/adsc.201901393⟩

International audience; From 2-iodo-N,N-diisopropylferrocenecarboxamide, the halogen 'dance' reaction was applied to deliver gram quantities of the 3-iodo isomer. The latter was successfully functionalized by Ullmann-type and Suzuki-Miyaura cross-cou

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02438541/document