Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework

Autor: Zhenzhong Lu, Harry G. W. Godfrey, Ivan da Silva, Yongqiang Cheng, Mathew Savage, Floriana Tuna, Eric J. L. McInnes, Simon J. Teat, Kevin J. Gagnon, Mark D. Frogley, Pascal Manuel, Svemir Rudić, Anibal J. Ramirez-Cuesta, Timothy L. Easun, Sihai Yang, Martin Schröder

Publikováno v: Nature Communications, Vol 8, Iss 1, Pp 1-10 (2017)

Gaining molecular-level insight into host–guest binding interactions is fundamentally important, but experimentally challenging. Here, Schröder and co-workers study CO2–host hydrogen bonding interactions in a pair of isostructural redox-active V

Externí odkaz: https://doaj.org/article/d102796e45484256907a08dab1dbe753

Selective signalling of alcohols by a molecular lattice and mechanism of single-crystal-to-single-crystal transformations

Autor: Leoní A. Barrios, Guillem Aromí, Benjamin Barth, Gavin A. Craig, Simon J. Teat, Kevin J. Gagnon, Olivier Roubeau, José Sánchez Costa, Santiago Rodríguez-Jiménez, Christine M. Beavers

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Dipòsit Digital de la UB
Universidad de Barcelona

Single-crystal-to-single-crystal (SCSC) transformations of molecular materials involving exchange of lattice molecules are becoming commonplace and very relevant in areas like chemical sensing or the pharmaceutical sector. Spin crossover (SCO) comple

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::63e0bcb260e4329c738bdaee92843e81
https://doi.org/10.1039/d0qi00645a

Magneto-structural studies of an unusual [MnIIIMnIIGdIII(OR)4]4- partial cubane from 2,2'-bis-p-tBu-calix[4]arene

Autor: Sergio Sanz, Simon J. Teat, Marco Coletta, Daniel J. Cutler, Euan K. Brechin, Kevin J. Gagnon, Mukesh Kumar Singh, Scott J. Dalgarno

Publikováno v: Dalton transactions (Cambridge, England : 2003), vol 49, iss 42
Dalton Transactions
Coletta, M, Sanz, S, Cutler, D J, Teat, S J, Gagnon, K J, Singh, M K, Brechin, E K & Dalgarno, S J 2020, ' Magneto-structural studies of an unusual [MnIIIMnIIGdIII(OR)4]4− partial cubane from 2,2′-bis-p-tBu-calix[4]arene ', Dalton Transactions . https://doi.org/10.1039/D0DT02731F

Reaction of 2,2'-bis-p-tBu-calix[4]arene (H8L) with MnCl2·4H2O, GdCl3·6H2O and 2,6-pyridinedimethanol (H2pdm) affords [MnIIIMnIIGdIII(H3L)(pdmH)(pdm)(MeOH)2(dmf)]·3MeCN·dmf (3·3MeCN·dmf) upon vapour diffusion of MeCN into the basic dmf/MeOH mot

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7db2eedc45658350be457c360e217ac7
https://escholarship.org/uc/item/4148t8qb

Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN–PtII Complex

Autor: Kevin J. Gagnon, Abraham B. Alemayehu, Abhik Ghosh, Jesper Bendix, Anders Reinholdt

Publikováno v: Inorganic Chemistry
Reinholdt, A, Alemayehu, A B, Gagnon, K J, Bendix, J & Ghosh, A 2020, ' Electrophilic Activation of Osmium-Nitrido Corroles : The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic Os VI N-Pt II Complex ', Inorganic Chemistry, vol. 59, pp. 5276-5280 . https://doi.org/10.1021/acs.inorgchem.0c00654

Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrol

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9c283427933e82deade53e986e78f984
https://hdl.handle.net/10037/27113

Cobalt- and Rhodium-Corrole-Triphenylphosphine Complexes Revisited: The Question of a Noninnocent Corrole

Autor: Sumit Ganguly, Kevin J. Gagnon, Ritimukta Sarangi, Diemo Renz, Laura J. McCormick, Logan J. Giles, Abhik Ghosh, Jeanet Conradie

Publikováno v: Inorganic chemistry, vol 56, iss 24
Ganguly, S; Renz, D; Giles, LJ; Gagnon, KJ; McCormick, LJ; Conradie, J; et al.(2017). Cobalt-and Rhodium-Corrole-Triphenylphosphine Complexes Revisited: The Question of a Noninnocent Corrole. Inorganic Chemistry, 56(24), 14788-14800. doi: 10.1021/acs.inorgchem.7b01828. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/9kd4m3hp

© 2017 American Chemical Society. A reinvestigation of cobalt-corrole-triphenylphosphine complexes has yielded an unexpectedly subtle picture of their electronic structures. UV-vis absorption spectroscopy, skeletal bond length alternations observed

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::96f4293331d03f5e0a090af37a03d320
https://doi.org/10.1021/acs.inorgchem.7b01828