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of 10
pro vyhledávání: '"Kevin Grollier"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 3032-3037 (2020)
We report herein a practical method to generate CF3Se− (and RFSe−) anions from shelf-stable reagents under iodide activation. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluo
Externí odkaz:
https://doaj.org/article/13fb38de302f49e489435baa7da1990f
Autor:
Arnaud de Zordo‐Banliat, Kevin Grollier, Nicolas Vanthuyne, Sébastien Floquet, Thierry Billard, Guillaume Dagousset, Bruce Pégot, Emmanuel Magnier
Publikováno v:
Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2023, 62 (12), ⟨10.1002/anie.202300951⟩
Angewandte Chemie International Edition, 2023, 62 (12), ⟨10.1002/anie.202300951⟩
Autor:
Arnaud de Zordo‐Banliat, Kevin Grollier, Jordan Vigier, Erwann Jeanneau, Guillaume Dagousset, Bruce Pegot, Emmanuel Magnier, Thierry Billard
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(63)
Trifluorometylselenolation via C-H activation is barely described in literature. In particular, no such vinylic functionalization has been yet described. Herein, a palladium-catalyzed trifluoromethylselenolation of vinylic C-H bonds is described. The
Autor:
Kevin Grollier, Arnaud De Zordo-Banliat, Flavien Bourdreux, Guillaume Dagousset, Emmanuel Magnier, Thierry Billard, Bruce Pégot
Publikováno v:
Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, In press, ⟨10.1002/chem.202100053⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, 27 (19), pp.6028-6033. ⟨10.1002/chem.202100053⟩
Chemistry-A European Journal, Wiley-VCH Verlag, In press, ⟨10.1002/chem.202100053⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, 27 (19), pp.6028-6033. ⟨10.1002/chem.202100053⟩
International audience; The synthesis of molecules bearing (trifluoromethylselenyl)methylchalcogenyl groups is described via an efficient two-step strategy based on a metal-free photoredox catalyzed decarboxylative trifluoromethylselenolation with go
Autor:
Kevin Grollier, Clément Ghiazza, Anis Tlili, Thierry Billard, Maurice Médebielle, Julien C. Vantourout
Publikováno v:
European Journal of Organic Chemistry. 2022
Autor:
Emmanuel Magnier, Guillaume Dagousset, Arnaud De-Zordo Banliat, Aurélie Damond, Thierry Billard, Kevin Grollier, Bruce Pégot
Publikováno v:
Tetrahedron
Tetrahedron, Elsevier, 2021, 101, pp.132507. ⟨10.1016/j.tet.2021.132507⟩
Tetrahedron, Elsevier, 2021, 101, pp.132507. ⟨10.1016/j.tet.2021.132507⟩
International audience; Available online-1-n-butyl-3-methylimidazolium selenocyanate ([bmim][SeCN]) proved to be a very efficient reagent for selenocyanation of alkyl halides. As part of an eco-friendly process, no organic solvents were used during t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4e4d19d8cfe2609ac9766b092f280aa6
https://hal.archives-ouvertes.fr/hal-03429484
https://hal.archives-ouvertes.fr/hal-03429484
Publikováno v:
Chemistry-A European Journal
Chemistry-A European Journal, 2021, 27 (50), pp.12910-12916. ⟨10.1002/chem.202102121⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, ⟨10.1002/chem.202102121⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, 27 (50), pp.12910-12916. ⟨10.1002/chem.202102121⟩
Chemistry-A European Journal, 2021, 27 (50), pp.12910-12916. ⟨10.1002/chem.202102121⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, ⟨10.1002/chem.202102121⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, 27 (50), pp.12910-12916. ⟨10.1002/chem.202102121⟩
International audience; The synthesis of trifluoromethylselenolated aromatic molecules via an auxiliary-assisted, palladium catalyzed, C−H bonds functionalization with trifluoromethyl tolueneselenosulfonate as reagent is described. The mono- or bis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce1a69bbccc4ba03fb4d724a1ad0af0f
https://hal.science/hal-03407550
https://hal.science/hal-03407550
Thermomorphic Polyethylene‐Supported Organocatalysts for the Valorization of Vegetable Oils and CO 2
Autor:
Sébastien Norsic, Killian Onida, Nam Duc Vu, Ayman Akhdar, Franck D'Agosto, Nicolas Duguet, Christophe Boisson, Kevin Grollier
Publikováno v:
Advanced Sustainable Systems
Advanced Sustainable Systems, Wiley, 2021, 5 (2), pp.2000218. ⟨10.1002/adsu.202000218⟩
Advanced Sustainable Systems, Wiley, 2021, 5 (2), pp.2000218. ⟨10.1002/adsu.202000218⟩
International audience; A range of thermomorphic polyethylene-supported organocatalysts is prepared from N-alkyl imidazoles and polyethylene iodide (PE) with good yields (85–92%) and high funtionality (98–99%). The catalytic activity of these spe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a08e036628fbfb39b9e0a4c7d9fcef1a
https://hal.archives-ouvertes.fr/hal-03245780/document
https://hal.archives-ouvertes.fr/hal-03245780/document
Publikováno v:
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2020, 16, pp.3032-3037. ⟨10.3762/bjoc.16.252⟩
Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 3032-3037 (2020)
Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2020, 16, pp.3032-3037. ⟨10.3762/bjoc.16.252⟩
Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 3032-3037 (2020)
We report herein a practical method to generate CF3Se− (and RFSe−) anions from shelf-stable reagents under iodide activation. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4d5cc9ab5a6e13700e983088510c4367
https://hal.archives-ouvertes.fr/hal-03097741/document
https://hal.archives-ouvertes.fr/hal-03097741/document
Autor:
Guillaume Dagousset, Emmanuel Chefdeville, Bruce Pégot, Thierry Billard, Arnaud De Zordo-Banliat, Emmanuel Magnier, Kevin Grollier
Publikováno v:
Tetrahedron
Tetrahedron, Elsevier, 2021, pp.132498. ⟨10.1016/j.tet.2021.132498⟩
Tetrahedron, Elsevier, 2021, pp.132498. ⟨10.1016/j.tet.2021.132498⟩
International audience; Trifluoromethyl tolueneselenosulfonate is a versatile reagent which can be reduced by iron powder to generate in situ trifluoromethylselenolate anion. This species can then react with alkyl bromide to perform SN2 reaction.