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Autor:
Cornelia Bohne, Anushree Das, August A. Garofoli, Jeanette A. Krause, Anna D. Gudmundsdottir, Kevin A. Chavez, Suma S. Thomas
Publikováno v:
Photochemistry and photobiology. 95(1)
Laser flash photolysis of ketone 1 in argon-saturated methanol yields triplet biradical 1BR (τ = 63 ns) that intersystem crosses to form photoenols Z-1P (λmax = 350 nm, τ ~ 10 μs) and E-1P (λmax = 350 nm, τ > 6 ms). The activation barrier for Z