Výsledky vyhledávání - "Kerry L. Verhorevoort"

Nucleophilic substitution vs. acid–base reactions of [Mn{N(SiMe3)2}2]·2thf; syntheses and structures of 2[Li(thf )4]+[Mn(C12H 8N)4]2−·C6 H5Me and [Mn(C12H8N)2]·3thf (thf = tetrahydrofuran, C12H8N = carbazol-9-yl)

Autor: Dominic S. Wright, Paul R. Raithby, Kerry L. Verhorevoort, Michael A. Beswick, Alexander Steiner, Christopher N. Harmer

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :2029-2032

The ion-separated complex 2[Li(thf) 4 ] + [Mn(C 12 H 8 N) 4 ] 2- 1 has been obtained from the nucleophilic substitution reaction of [Mn{N(SiMe 3 ) 2 } 2 ]·2thf with Li[C 12 H 8 N] (1∶4 equivalents) (thf = tetrahydrofuran, C 12 H 8 N = carbazol-9-y

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7e62778f5fa3c70e6f02549f213c0a44
https://doi.org/10.1039/a700765e

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Syntheses and structural studies of two adducts of cadmocene, [CdCp2. TMEDA] and [CdCp2. PMDETA] (TMEDA  Me2NCH2CH2NMe2, PMDETA  (Me2NCH2CH2)2NMe)

Autor: Kerry L. Verhorevoort, Domonic S. Wright, Andrew J. Edwards, Moira-Ann Rennie, Paul R. Raithby, Donald Barr

Publikováno v: Journal of Organometallic Chemistry. 493:175-179

Cp 2 Cd.TMEDA 1 and Cp 2 Cd.PMDETA 2 have been synthesized and characterized by spectroscopic studies and by X-ray diffraction studies at low-temperature (153 K). The adducts are present in the crystals as mononuclear complexes. When the denticity of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4fdf74641687c1ff2c9093d65d2919bc
https://doi.org/10.1016/0022-328x(95)05325-j

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Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: synthesis and crystal structure of [naphthylN·NN·NC(S)]2Ba·3HMPA

Autor: Ronald Snaith, Dominic S. Wright, F. Adele Banbury, Kerry L. Verhorevoort, Matthew G. Davidson, Avelino Martín, Paul R. Raithby

Publikováno v: J. Chem. Soc., Chem. Commun.. :1152-1154

Solid Ba(OH)2 suspended in toluene containing HMPA [OP(NMe2)3] reacts with the 5-aminothiatriazole, naphthyl NH·[graphic omitted], to give the monomeric 5-mercaptotetrazolylbarium complex, [naphthlyl [graphic omitted]a·3HMPA, 1; the isolation and s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::554cc0712da50c712dcf4c5e20c4dd9e
https://doi.org/10.1039/c39920001152

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Metal selection of ligand functionality in [(mes)2P(O)2Li·2thf]2 and [{(Me3Si)2N}Cd{(mes)2P O}2Li·2thf] (mes = C6H2Me3-2,4,6)

Autor: Michael A. Beswick, Julie S. Palmer, Kerry L. Verhorevoort, Alexander Steiner, Paul R. Raithby, Dominic S. Wright, Natalie L. Cromhout, Christopher N. Harmer

Publikováno v: Chemical Communications. :583-584

The reaction of LiBu n with [(mes) 2 P(H)O] affords the diorganophosphinate complex [(mes) 2 P(O) 2 Li·2thf] 1 and [(mes) 2 PLi], however, addition of [Cd{N(SiMe 3 ) 2 } 2 ] to the mixture gives the diorganophosphinite complex [{Me 3 - Si) 2 N}Cd{(m

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::68fb797995dc8f0cebd77f755166c1f7
https://doi.org/10.1039/a608202e

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Synthesis and structure of [{(Me3Si)2N}2Cd{(PhN)3C}Li2·3thf]; an unusual heterobimetallic co-complex containing three different metal coordination environments

Autor: Dominic S. Wright, Philip J. Bailey, Lindsey A. Mitchell, Paul R. Raithby, Kerry L. Verhorevoort, Moira Ann Rennie

Publikováno v: Chem. Commun.. :1351-1352

Dilithio-1,2,3-triphenylguanidide, [{(PhN)3C}Li2], reacts with [Cd{N(SiMe3)2}] to give [{(Me3Si)2N}2Cd{(PhN)3}Li2·3thf] 1; a novel co-complex containing three different metal coordination environments.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3b54b7e9fc3ea7501dca57eb8c8daafb
https://doi.org/10.1039/cc9960001351

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Selenium insertion into a cadmium–carbon bond; synthesis and structural characterisation of the loosely linked dimer [{Cd(SeCCPh)2(tmen)}2](tmen = Me2NCH2CH2NMe2)

Autor: Kerry L. Verhorevoort, Joanna C. Vallat, Alexander Steiner, Dominic S. Wright, Michael A. Beswick, Paul R. Raithby

Publikováno v: J. Chem. Soc., Dalton Trans.. :2183-2184

The heterogeneous reaction of elemental selenium with the monomeric complex [Cd(CCPh)2(tmen)](2:1 equivalents) produced the unusual loosely linked dimer [{Cd(SeCCPh)2(tmen)}2].

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8a28f4cd42998cd586fd0111372a93b0
https://doi.org/10.1039/dt9960002183

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A mixed organozinc–diorganophosphide complex containing protic phosphine ligands bonded to zinc

Autor: Alexander Steiner, Andrew J. Edwards, Michael A. Paver, Paul R. Raithby, Matthew G. Davidson, Dominic S. Wright, Kerry L. Verhorevoort, Christopher A. Russell

Publikováno v: J. Chem. Soc., Chem. Commun.. :1989-1990

Metallation of diphenylphosphine with ZnEt2(5:3 equiv. ) in thf produces {[EtZn(µ-PPh2)]3·(HPPh2)2·thf}1, which is shown by X-ray crystallography to have a Zn3P3 core in which Ph2PH ligands act as donors to two of the zinc centres.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d199ef8f63e3e74bfa558844165fb5cf
https://doi.org/10.1039/c39950001989

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A new halide-free route to metallo-organic cadmium complexes; syntheses and structural characterisations of [Cd(PhCC)2(tmeda)] and [Cd(C12H8N)4]2–·2Li(thf)4+(tmeda = Me2NCH2NMe2)

Autor: Andrew J. Edwards, Paul R. Raithby, Kerry L. Verhorevoort, Dominic S. Wright, Moira-Ann Rennie, Donald Barr

Publikováno v: J. Chem. Soc., Chem. Commun.. :1627-1628

The syntheses of the monomeric diorganocadmium complex [Cd(PhCC)2(tmeda)]1, the first structurally characterised Cd-acetylide, and of the ion-separated [Cd(C12H8N)4]2–·2Li(thf)4+2, containing a metallo-organic Cd dianion, from the nucleophilic sub

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b7e5bb3de51c666304535ab4e117d0e0
https://doi.org/10.1039/c39940001627

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