Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Kenton B. Renkema"'
Publikováno v:
Polyhedron. 25:459-468
Both MH(Ph)(CO)L2 (L = PtBu2Me; M = Ru and Os) react with vinyl fluoride to form M–F bonds; however, Ru eliminates benzene, while Os eliminates ethylene. In contrast, Ru(H)2(CO)L2 and Os(H)2(CO)(1-butene)L2 both react with vinyl fluoride to give et
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::315b8e3d1b6f0e655bf384b46ffe7fd9
https://doi.org/10.1016/j.poly.2005.08.012
https://doi.org/10.1016/j.poly.2005.08.012
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 224:125-131
The reactions of OsH(Ph)(CO)L 2 (L = P t Bu 2 Me) with HSiMe 3 , H 2 SiPh 2 or H 3 SiPh produce benzene and OsH 3 (silyl)(CO)L 2 , which is characterized as a fac -H 3 OsP 3 shape capped on the H 3 face by the silyl group. For H 2 SiPh 2 and H 3 SiPh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bfd73d0968551094822934dbc3879682
https://doi.org/10.1016/j.molcata.2004.07.028
https://doi.org/10.1016/j.molcata.2004.07.028
Autor:
Nadine Summa, Margaret Czerw, Karsten Krogh-Jespersen, Alan S. Goldman, Kenton B. Renkema, Patrick D. Achord
Publikováno v:
Journal of the American Chemical Society. 124:11404-11416
Pincer complexes of the type ((R)PCP)IrH(2), where ((R)PCP)Ir is [eta(3)-2,6-(R(2)PCH(2))(2)C(6)H(3)]Ir, are the most effective catalysts reported to date for the "acceptorless" dehydrogenation of alkanes to yield alkenes and free H(2). We calculate
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::183bb2c8e0cddbddea7f34a359d300d5
https://doi.org/10.1021/ja012460d
https://doi.org/10.1021/ja012460d
Autor:
Kenneth G. Caulton, Ramón Bosque, Feliu Maseras, William E. Streib, Kenton B. Renkema, Odile Eisenstein,‡ and
Publikováno v:
Journal of the American Chemical Society. 121:10895-10907
OsH(Ph)(CO)L2 (L = PtBu2Me, Ph = C6H5) is synthesized and studied by spectroscopic and DFT (B3LYP) calculations. It forms 1:1 adducts with CO or MeCN, but D2 causes reductive elimination of C6H6. Reaction with C6D6 gives exclusively OsD(C6D5)(CO)L2.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1815bbcbaeb93ceb369e2c4809ddffd8
https://doi.org/10.1021/ja990523a
https://doi.org/10.1021/ja990523a
Autor:
Masamichi Ogasawara, Kenneth G. Caulton, Kenton B. Renkema, John C. Huffman, William E. Streib
Publikováno v:
Inorganica Chimica Acta. 291:226-230
Reaction of anhydrous FeCl3 with PtBu2Me in alcohol gives [HPtBu2Me][FeCl3(PtBu2Me)], a salt with a tetrahedral Fe(II) anion hydrogen bonded (via Cl) to the P–H proton of the cation. Reaction of FeCl2(CO)4 with PtBu2Me in benzene, followed by worku
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7f850ce24f47d596d5777c59cc20df5e
https://doi.org/10.1016/s0020-1693(99)00104-8
https://doi.org/10.1016/s0020-1693(99)00104-8
Publikováno v:
Polyhedron. 18:2575-2578
A synthesis of the title compound by hydrolysis of OsH(C6H5)(CO)(PtBu2Me)2 has the advantage that the product shows 1H NMR spectra free of the influence of hydrogen bonding to water impurity. In the solid state, the hydroxyl group interacts weakly wi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6a1ee50de7099a6adaa843fd06527c4f
https://doi.org/10.1016/s0277-5387(99)00146-1
https://doi.org/10.1016/s0277-5387(99)00146-1
Autor:
Kenton B. Renkema, Kenneth G. Caulton
Publikováno v:
New Journal of Chemistry. 23:1027-1032
OsHCl(CO)L2 (L=PBu2tMe) is transformed to OsCl(NO)(CO)L2 by p-MeC6H4SO2N(NO)Me. Chloride removal with NaBAr4′ [Ar′=3,5-(CF3)2C6H3] yields the nonplanar, unsaturated Os(0) compound [Os(NO)(CO)L2]BAr4′, which is shown to be more reactive towards
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::279b169a692a03b1a3f3d291a4858e7a
https://doi.org/10.1039/a903799c
https://doi.org/10.1039/a903799c
Autor:
Susan K. Hendges, Fred W. Vance, Steven Ashley Snow, Michael E. Silver, Robin N. Redding, Ronald J. Matthews, Tammy L. Bush, Kenton B. Renkema, John C. Huffman
Publikováno v:
Inorganica Chimica Acta. 244:185-190
The novel mixed alkali metal silanolate K 4 Li 4 ( OSiMe 3 ) x ( OCMe 3 ) 8−x (x=6.8 ( 1 ), 5.7 ( 2 ), 8 ( 3 )) has been prepared via the reaction of hexamethyldisiloxane with n-butyllithium and potassium-butoxide in THF or by the reaction of KOSiM
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::363167041a176d1aaee303b14bd1d1e9
https://doi.org/10.1016/0020-1693(95)04781-6
https://doi.org/10.1016/0020-1693(95)04781-6
Autor:
Robin N. Redding, Ericka L. Lyszak, Michael S. Hermen, John C. Huffman, Michael E. Silver, Kenton B. Renkema, Susan K. Hendges, Jonathan P. O'Brien, David A. Kort, Tammy L. Bush
Publikováno v:
Organometallics. 12:338-342
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f5fb618b9ee06f5b774e35a28db29442
https://doi.org/10.1021/om00026a019
https://doi.org/10.1021/om00026a019
Publikováno v:
ChemInform. 36
The mechanism of (PCP)Ir-catalyzed transferdehydrogenation and a full free-energy profile have been elucidated for the substrate/acceptor couple COA/TBE (COA = cyclooctane; TBE = t-butylethylene). Stoichiometric components of the catalytic cycle have
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ebbb086f11c31dc745ec3908488571c2
https://doi.org/10.1002/chin.200504269
https://doi.org/10.1002/chin.200504269