Výsledky vyhledávání - "Kenney, J. F."

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The Evolution of Multicomponent Systems at High Pressures: II. The Alder-Wainwright, High-Density, Gas-Solid Phase Transition of the Hard-Sphere Fluid

Autor: Kenney, J. F.

Publikováno v: Phys. Chem. Chem. Phys., 1999, 1, 3277-3285

The thermodynamic stability of the hard-sphere gas has been examined, using the formalism of scaled particle theory [SPT], and by applying explicitly the conditions of stability required by both the second and third laws of thermodynamics. The temper

Externí odkaz: http://arxiv.org/abs/cond-mat/0505080

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The Evolution of Multicomponent Systems at High Pressures: IV. The Genesis of Optical Activity in High-density, Abiotic Fluids

Autor: Kenney, J. F., Deiters, Ulrich K.

Publikováno v: Phys. Chem. Chem. Phys., 2000, 2, 3163-3174

A thermodynamic argument has been developed which relates the chirality of the constituents of a mixture of enantiomers to the system excess volume, and thereby to its Gibbs free enthalpy. A specific connection is shown between the excess volume and

Externí odkaz: http://arxiv.org/abs/cond-mat/0505077

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The Evolution of Multicomponent Systems at High Pressures: VI. The Thermodynamic Stability of the Hydrogen-Carbon System: The Genesis of Hydrocarbons and the Origin of Petroleum

Autor: Kenney, J. F., Kutcherov, Vladimir G., Bendeliani, Nikolai A., Alekseev, Vladimir A.

Publikováno v: Proceedings of the National Academy of Sciences (USA), 2002, 99/17, 10976-10981

The spontaneous genesis of hydrocarbons which comprise natural petroleum have been analyzed by chemical thermodynamic stability theory. The constraints imposed upon chemical evolution by the second law of thermodynamics are briefly reviewed; and the

Externí odkaz: http://arxiv.org/abs/physics/0505003

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Development of a general equation of state for real molecules in arbitrary regimes of temperature and pressure: I. The hard-core reference system

Autor: Kenney, J. F., Petti, Richard J.

A general equation of state for the hard-body reference system of real fluid has been developed from first principles, statistical mechanical arguments using metric differential geometry to describe the "available volume," V0, and its determining sur

Externí odkaz: http://arxiv.org/abs/physics/0504200

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The microcanonical thermodynamics of finite systems: The microscopic origin of condensation and phase separations; and the conditions for heat flow from lower to higher temperatures

Autor: Gross, D. H. E., Kenney, J. F.

Publikováno v: J.Chem.Phys. 122 (2005) 224111

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical mechanics espec

Externí odkaz: http://arxiv.org/abs/cond-mat/0503604

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