Zobrazeno 1 - 10
of 37
pro vyhledávání: '"Kenneth W. Barnett"'
Publikováno v:
Inorganic Chemistry. 17:486-489
Publikováno v:
Journal of Organometallic Chemistry. 69:121-130
The complexes trans -( h 5 -C 5 H 5 )M(CO) 2 (L)COCH 3 [M = Cr, L = P(C 6 H 5 ) 3 , P( p -CH 3 OC 6 H 4 ) 3 , P(C 6 H 5 )(CH 3 ) 2 ; M = W, L = P(C 6 H 5 ) 3 , P( p -CH 3 OC 6 H 4 ) 3 , P(C 6 H 5 )(CH 3 ) 2 , P(n-C 4 H 9 ) 3 ] have been synthesized b
Autor:
James D. McClure, Kenneth W. Barnett
Publikováno v:
Journal of Organometallic Chemistry. 80:385-393
(π-Cyclopentenyl)(π-cyclopentadienyl)nickel, (h5-C5H5)Ni(h3-C5H7), is a novel, highly active, unicomponent catalyst for the conversion of ethylene to n-butenes and n-hexenes at 145–150° C. At high conversions of ethylene (70–90%), the dimeric
Autor:
Kenneth W. Barnett, David L. Beach
Publikováno v:
Journal of Organometallic Chemistry. 142:225-232
Tris(triphenylphosphine)rhodium(I) chloride in the presence of oxygencatalyzes the rearrangement of bicyclo[3.1.O]hex-2-enes, producing cyclohexadienes. Rearrangement rates are increased by introduction of methyl or carboxymethyl substituents at C6,
Autor:
Kenneth W. Barnett, Thomas G. Pollmann
Publikováno v:
Journal of Organometallic Chemistry. 69:413-421
The molybdenum acetyl complexes trans-(h5 -C5H5)Mo(CO)2 (L)COCH3 (L = a tertiary phosphine) are thermally decarbonylated in a variety of solvents to the corresponding methyl derivatives (h5-C5H5)Mo(CO)2(L)CH3. Reaction rates are independent of the so
Publikováno v:
Journal of Organometallic Chemistry. 154:151-157
Carbon-13 NMR spectral data for complexes having the general formula CpM(CO)nX (Cp = η5-C5H5; M = Mo or W, n = 3; M = Fe, n = 2; X = halogen, methyl or acetyl) and their phosphine and isocyanide substitution products are reported. For CpM(CO)3X comp
Publikováno v:
Journal of Organometallic Chemistry. 142:211-223
The rhodium complexes Rh(PPh 3 ) 3 Cl and Rh(PPh 3 ) 2 (CO)Cl catalyze the ring opening of endo -6-carbomethoxybicyclo[3.1.0]hex-2-ene (I) forming the five possible isomeric carbomethoxycyclohexadienes II–VI. The rate of the reaction is dramaticall
Autor:
Kenneth W. Barnett, Donna G. Alway
Publikováno v:
Inorganic Chemistry. 19:1533-1543
Autor:
Kenneth W. Barnett, David L. Beach
Publikováno v:
Journal of Organometallic Chemistry. 97:C27-C30
Pure cis - and trans -(η 5 -C 5 H 5 )M(CO) 2 [P(C 6 H 5 ) 3 ]X (M = Mo, X = I or Br; M = W, X = I) have been separated by chromatographic methods. Stereochemical assignments are made on the basis of infrared and 1 H and 13 C NMR spectroscopy. Mechan
Autor:
Kenneth W. Barnett, Donna G. Alway
Publikováno v:
Inorganic Chemistry. 17:2826-2831
Der prim. photochemische Prozes (366 oder 436 nm) fur das Bromo- und Iodo-Derivat (I) (X: Br, I) ist die Dissoziation von CO.