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pro vyhledávání: '"Kenneth N, MacDougall"'
Autor:
Kenneth N. MacDougall, Sigitas Stončius, Andrei V. Malkov, Grant D. McGeoch, Andrea Mariani, Pavel Kocovsky
Publikováno v:
Tetrahedron. 62:264-284
Asymmetric reduction of N-aryl ketimines 1a–k, 43, and 45 with trichlorosilane can be catalyzed by new N-methyl l-amino acid-derived Lewis-basic organocatalysts, such as the valine-derived bisamide 3d (10 mol%), in toluene at room temperature with
Publikováno v:
ChemInform. 35
Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by a new N-methyl l-valine derived Lewis basic organocatalyst, such as 4d, with high enantioselectivity. The structure−reactivity investigation suggests hydrogen bonding and
Publikováno v:
Organic letters. 6(13)
[reaction: see text] Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by a new N-methyl L-valine derived Lewis basic organocatalyst, such as 4d, with high enantioselectivity. The structure-reactivity investigation suggests hy