Výsledky vyhledávání - "Kenneth Gene Moloy"

Lysinol: a renewably resourced alternative to petrochemical polyamines and aminoalcohols

Autor: Pranit S. Metkar, Kenneth Gene Moloy, Mark A. Scialdone

Publikováno v: Green Chem.. 16:4575-4586

This paper reports the preparation of lysinol (2,6-diamino-1-hexanol) by the hydrogenation of lysine and an example of its use as a replacement for petrochemical-derived amines. Lysine is presently manufactured by fermentation of sugars and other car

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a6d5d1c16d340fc6417710f458dad4bd
https://doi.org/10.1039/c4gc01167h

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Fluorinated Pyridinium and Ammonium Cationic Surfactants

Autor: Charles Taylor, Tim Coope, Sheng Peng, Kenneth Gene Moloy, Tanya Corder, Ming Hung, Allison Yake

Publikováno v: Yake, A, Corder, T, Moloy, K, Coope, T, Taylor, C, Hung, M & Pung, S 2016, ' Fluorinated Pyridinium and Ammonium Cationic Surfactants ', Journal of Fluorine Chemistry, vol. 187, pp. 46-55 . https://doi.org/10.1016/j.jfluchem.2016.05.003

New classes of partially fluorinated cationic surfactants, including pyridinium sulfonates and ammonium hydrochlorides have been prepared in which a fluoroalkyl chain is interrupted either by ether oxygen (—O—), or by methylene (—CH2—) units.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8ad04b6ae08979f59e8ba0595de67ca1
https://hdl.handle.net/1983/a676f1c7-9ab8-401d-823f-d04de4716d31

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The gem-Dialkyl Effect as a Test for Preliminary Diphosphine Chelate Opening in a Reductive Elimination Reaction

Autor: Karen I. Goldberg, Kenneth Gene Moloy, Qi L. Wang, Dawn M. Bregel, and Bridget A. O'Neill, Kathryn L. Arthur, Nicole A. Smythe

Publikováno v: Organometallics. 24:4624-4628

A significant kinetic effect of the placement of gem-dialkyl substituents in the carbon backbone of a bidentate phosphine ligand on a reductive elimination reaction involving chelate opening as a preliminary step has been documented. This observation

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::97f0a565fdfd719f14f23a2b15530f7d
https://doi.org/10.1021/om0500467

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Porogen and Cross-Linking Effects on the Surface Area, Pore Volume Distribution, and Morphology of Macroporous Polymers Obtained by Bulk Polymerization

Autor: Michel R. Gagné, Brian P. Santora, Kenneth Gene Moloy, Nora Sabina Radu

Publikováno v: Macromolecules. 34:658-661

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::77712a929d44c6e405b20a5fb468b71f
https://doi.org/10.1021/ma0004817

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Computational Assessment of the Effect of σ−π Bonding Synergy and Reorganization Energies on Experimental Trends in Rhodium−Phosphine Bond Enthalpies

Autor: Chris E. Wozniak, Kenneth Gene Moloy, and Jamal Uddin, Steven Feldgus, Clark R. Landis

Publikováno v: Organometallics. 19:4878-4886

Via a series of systematic density functional (B3LYP/LANL2DZ) computational experiments, we have examined the origin of opposing Rh−PR3 bond enthalpy trends involving two different square-planar Rh(I) complexes with a series of different π-accepti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8bdea2c72f63369b62e1aa821b68026b
https://doi.org/10.1021/om000544+

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Synthetic, Structural, and Solution Calorimetric Studies of Pt(CH3)2(PP) Complexes

Autor: Edwin D. Stevens, William J. Marshall, Dale C. Smith, Kenneth Gene Moloy, Christopher M. Haar, Steven P. Nolan

Publikováno v: Organometallics. 19:1427-1433

Reaction enthalpies of the complex (COD)PtMe2 (1; COD = eta(4)-1,5-cyclooctadiene) with an extensive series of bidentate phosphines (dpype, dppf, diop, dppe, dppb, dppp, dpmcb, depe, dmpe, dcpce) have been measured by solution calorimetry. The relati

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::48bb9206d2a0ac8f1b9396c72961dccb
https://doi.org/10.1021/om990962i

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Synthetic, Structural, and Solution Thermochemical Studies in the Dimethylbis(phosphine)platinum(II) System. Dichotomy between Structural and Thermodynamic Trends

Autor: Christopher M. Haar, Kenneth Gene Moloy, William J. Marshall, Alfred Prock, Warren P. Giering, Steven P. Nolan

Publikováno v: Organometallics. 18:474-479

Reaction enthalpies of the complex (COD)PtMe2 (COD = η4-1,5-cyclooctadiene) with an extensive series of unidentate phosphines have been measured by solution calorimetry. The molecular structures of cis-P2PtMe2 for P = PEt3, PMe2Ph, P(pyrrolyl)3, and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::260626dd1104e280668a338cd3ae26f5
https://doi.org/10.1021/om9807001

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Thermodynamics of Phosphine Coordination to the [PNP]RhI Fragment: An Example of the Importance of Reorganization Energies in the Assessment of Metal−Ligand 'Bond Strengths'

Autor: Jinkun Huang, William J. Marshall, Steven P. Nolan, Christopher M. Haar, Kenneth Gene Moloy

Publikováno v: Journal of the American Chemical Society. 120:7806-7815

Reaction enthalpies of the complexes [RPNP]Rh(COE) ([RPNP] = N(SiMe2CH2PPh2)(2), N(SiMe2-(CH2PPr2)-Pr-i)(2); COE = cyclooctene) with a series of phosphine ligands and CO have been measured by solution calorimetry. The measured enthalpies span range o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::01d383f2ebc4814a8abeafc200657805
https://doi.org/10.1021/ja974200v

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N-Pyrrolyl Phosphines: Enhanced π-Acceptor Character via Carboalkoxy Substitution

Autor: Steven P. Nolan, Adrian Huang, William J. Marshall, Scafford A. Serron, Kenneth Gene Moloy, Kate L. Mason, John E. Marcone

Publikováno v: Organometallics. 16:3377-3380

A series of 3,4-dicarboethoxy-N-pyrrolyl phosphine ligands (R2P−NC4H2(CO2Et)2) is described. A number of techniques, including reaction calorimetry, infrared spectroscopy, and X-ray crystallography, demonstrate that these ligands are potent π-acce

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::79813f7b8b265c45f38e95395655b425
https://doi.org/10.1021/om970129q

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