Zobrazeno 1 - 10
of 481
pro vyhledávání: '"Kenneth D. Karlin"'
Autor:
Bohee Kim, Magdalene T. Brueggemeyer, Wesley J. Transue, Younwoo Park, Jaeheung Cho, Maxime A. Siegler, Edward I. Solomon, Kenneth D. Karlin
Publikováno v:
Journal of the American Chemical Society. 145:11735-11744
Autor:
Mayukh Bhadra, Therese Albert, Alicja Franke, Verena Josef, Ivana Ivanović-Burmazović, Marcel Swart, Pierre Moënne-Loccoz, Kenneth D. Karlin
Publikováno v:
Journal of the American Chemical Society. 145:2230-2242
Publikováno v:
Faraday Discuss
This paper overviews the Final Remarks lecture delivered (by K.D.K.) at the end of this bioinorganic chemistry Faraday Discussion, held online for a worldwide audience, January 31 – February 3, 2022. This paper provides discussion in six sections:
Autor:
Keith O. Hodgson, Maxime A. Siegler, Markus Lerch, Kenneth D. Karlin, Wesley J. Transue, Jung Yoon C. Lee, Britt Hedman, Siegfried Schindler, Adam Neuba, Patrick Josephs, Ryan E. Cowley, Mayukh Bhadra, Hyeongtaek Lim, Gerald Henkel, Edward I. Solomon
Publikováno v:
J Am Chem Soc
The central role of cupric superoxide intermediates proposed in hormone and neurotransmitter biosynthesis by noncoupled binuclear copper monooxygenases like dopamine-β-monooxygenase has drawn significant attention to the unusual methionine ligation
Autor:
Bernard Meunier, Gary Brudvig, Jennifer L Mclain, Shun-ichi Murahashi, V L Pecoraro, D Riley, Anne Robert, J A Rodriguez, R A Sheldon, J S Valentine, C Young, James M Mayer, Julian Limburg, Jinbo Lee, Diane Cabelli, R H Crabtree, Sergiu M Gorun, John T Groves, Zhengbo Hu, K U Ingold, Kenneth D Karlin, Naruyoshi Komiya, Marie-aude Kopf, Hans Jorg Krueger, H Zhu
Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding rese
Autor:
Kenneth D. Karlin, Edward I. Solomon, Patrick J. Rogler, Hyun Kim, Savita Sharma, Andrew W. Schaefer
Publikováno v:
Journal of the American Chemical Society. 142:3104-3116
Establishing redox and thermodynamic relationships between metal-ion-bound O2 and its reduced (and protonated) derivatives is critically important for a full understanding of (bio)chemical processes involving dioxygen processing. Here, a ferric heme
Publikováno v:
J Am Chem Soc
In this report, we investigate the physical and chemical properties of monocopper Cu(I) superoxo and Cu(II) peroxo and hydroperoxo complexes. These are prepared by cryoreduction/annealing of the parent [LCu(I)(O(2))](+) Cu(I) dioxygen adducts with th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a4e2ce5f08b7267ddf6ff5d9765f2ac0
https://europepmc.org/articles/PMC8785356/
https://europepmc.org/articles/PMC8785356/
Publikováno v:
Inorg Chem
The efficiency of the hydrogen evolution reaction (HER) can be facilitated by the presence of proton-transfer groups in the vicinity of the catalyst. A systematic investigation of the nature of the proton-transfer groups present and their interplay w
Publikováno v:
Inorganic Chemistry. 58:15423-15432
The focus of this study is in the description of synthetic heme/copper/O2 chemistry employing a heme-containing binucleating ligand which provides a tridentate chelate for copper ion binding. The a...
Autor:
Edward I. Solomon, Daniel E. Diaz, Mayukh Bhadra, David A. Quist, Kenneth D. Karlin, Ioannis Kipouros, Andrew W. Schaefer, Austin E. Herzog
Publikováno v:
Angew Chem Int Ed Engl
The dioxygen reactivity of a series of TMPA-based copper(I) complexes (TMPA=tris(2-pyridylmethyl)amine), with and without secondary-coordination-sphere hydrogen-bonding moieties, was studied at -135 °C in 2-methyltetrahydrofuran (MeTHF). Kinetic sta