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Autor:
Kazuhide Koike, Koji Takeuchi, Hisao Hori, Masakazu Ishizuka, Kengo Enjouji, Osamu Ishitani, Takashi Ibusuki, Jeremy R. Westwell, Hideo Konno, Kazuhiko Sakamoto
Publikováno v:
Scopus-Elsevier
Reduction of CO2 to CO was efficiently photocatalyzed by [Re(4,4‘-X2bpy)(CO)3PR3]+ (X = H, Me; PR3 = P(OEt)3, P(O-i-Pr)3) in quantum yields of 0.16−0.20. Complexes with CF3 as X or trialkylphosphine as PR3 have much lower photocatalytic ability.