Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Kelsey R. Brereton"'
Autor:
David M. Tiede, Kelsey R. Brereton, David M. Kaphan, Rachel C. Klet, Karen L. Mulfort, Massimiliano Delferro, Ryan J. Witzke, Alexander J. M. Miller
Publikováno v:
Organometallics. 40:1482-1491
Publikováno v:
Polyhedron. 226:116089
Autor:
Ashley E. Fricker, Erika Samolova, Arnold L. Rheingold, David B. Green, Kelsey R. Brereton, Joseph M. Fritsch
Publikováno v:
Polyhedron. 223:115946
Publikováno v:
Organometallics. 38:3104-3110
Insights into the influence of solvent on hydride transfer emerge from a study of iridium complexes with the formula [Cp*Ir(bpy-X)H]+ (bpy-X = 4,4′-X2-2,2′-bipyridine, X = H, Me, tBu, OMe, CO2Me, a...
Publikováno v:
Chemical Society reviews. 49(22)
The prevalence of transition metal-mediated hydride transfer reactions in chemical synthesis, catalysis, and biology has inspired the development of methods for characterizing the reactivity of transition metal hydride complexes. Thermodynamic hydric
Publikováno v:
ACS Energy Letters. 3:1128-1136
The light-driven synthesis of fuels requires efficient coupling of photon absorption with bond-forming chemical reactions. Molecular photoelectrocatalysis is an emerging approach in solar fuel production based on single molecules that support electro
Autor:
Arnold L. Rheingold, Kelsey R. Brereton, Amanda E. Stahl, Angela M. Longo, Joseph M. Fritsch, David B. Green, Alexandria M. McCollum, Abigail S. Butler, Thomas R. Cundari
Publikováno v:
Polyhedron. 204:115233
Three ketoimines with pendant quinolyl moieties and a series of five-coordinate ketoiminate aluminum complexes were prepared and characterized spectroscopically and crystallographically. The synthesis of the ketoimines completed a series of ten regio
Autor:
Sarina M. Bellows, Alexander J. M. Miller, Thomas R. Cundari, Robert M. Adams, Antonio A. Lopez, William D. Jones, Hengameh Fallah, Kelsey R. Brereton
Publikováno v:
The Journal of Physical Chemistry B. 120:12911-12919
Hydricity, or hydride donating ability, is a thermodynamic value that helps define the reactivity of transition metal hydrides. To avoid some of the challenges of experimental hydricity measurements in water, a computational method for the determinat
Publikováno v:
Inorganic Chemistry. 55:12042-12051
The hydricity of the heterobimetallic iridium/ruthenium catalyst [Cp*Ir(H)(μ-bpm)Ru(bpy)2]3+ (1, where Cp* = η5-pentamethylcyclopentadienyl, bpm = 2,2′-bipyrimidine, and bpy = 2,2′-bipyridine) has been determined in both acetonitrile (63.1 kcal
Publikováno v:
Journal of the American Chemical Society
Aqueous hydride transfer is a fundamental step in emerging alternative energy transformations such as H2 evolution and CO2 reduction. "Hydricity," the hydride donor ability of a species, is a key metric for understanding transition metal hydride reac