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pro vyhledávání: '"Kelsey A. Schulte"'
Publikováno v:
Chemical Science. 9:9018-9026
Geometric control in mononuclear complexes has come to the forefront in the field of molecular magnets due to its profound effects on relaxation pathways and blocking temperature in single molecule magnets (SMMs). Herein we report the synthesis and m
Publikováno v:
Chemistry – A European Journal. 23:3548-3552
A family of distorted trigonal pyramidal transition-metal complexes [MII (N3 N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single-molecule magnets. Magnetic anisotropy of the family depends on the electronic configurat
Autor:
Kelsey A. Schulte, Alessandro Soncini, Willem Van den Heuvel, Mohamed Saber, Andrew J. Brown, Kim R. Dunbar
Publikováno v:
Inorganic Chemistry. 56:1031-1035
The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the mol
Publikováno v:
Chemical communications (Cambridge, England). 54(72)
A new family of mononuclear lanthanide complexes, where the eight coordinate lanthanide ions adopt a very rare cubic coordination geometry is reported. The Dy analogue exhibits SMM behavior with a Ueff value 95.7 K under a 0.02 T applied dc field. Ab
Publikováno v:
Polyhedron. 85:560-564
Reported herein are the magnetic and structural properties as well as solution equilibrium investigation for a pair of iron (II) pyridyl-imidazoline complexes: [Fe(pizMe)Cl2]2 (1) and [Fe(pizMe)3](FeCl4) (2), where pizMe = 2-(2′-pyridinyl)-4,5-dihy
Autor:
Matthew P. Shores, Kelsey A. Schulte, Christina M. Klug, Brian S. Newell, Stephanie R. Fiedler, Ashley M. McDaniel
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 41(40)
We report the syntheses, characterisations, and spin state behaviours of salts of the tripodal-ligated Fe(II) complex [FeL(6-OH)]X(2) (L(6-OH) = tris{4-[(6-methanol)-2-pyridyl]-3-aza-3-butenyl}amine, X = OTf(-) (1), Br(-) (2), I(-) (3), BPh(4)(-) (4)