Zobrazeno 1 - 10
of 292
pro vyhledávání: '"Keith U. Ingold"'
Publikováno v:
Archives of biochemistry and biophysics. 726
The concentrations of lipid-soluble, chain-breaking antioxidants in human plasma and in erythrocyte ghosts have been determined for the first time by an inhibited autoxidation method. The results are very similar to the concentrations of vitamin E me
Publikováno v:
Angewandte Chemie. 130:9284-9288
In 1923, Wieland and Wingler reported that in the molecular hydrogen producing reaction of hydrogen peroxide with formaldehyde in basic solution, free hydrogen atoms (H. ) are not involved. They postulated that bis(hydroxymethyl)peroxide, HOCH2 OOCH2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::64e295b6e7f9f501db67889b83961196
https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&origin=inward&scp=85046127775
https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&origin=inward&scp=85046127775
Publikováno v:
Journal of the American Chemical Society. 137:94-97
Hydrogen atom transfer is central to many important radical chain sequences. We report here a method for determination of both the primary and secondary isotope effects for symmetrical substrates by the use of NMR. Intramolecular competition reaction
Autor:
Luca Valgimigli, Keith U. Ingold, Derek A. Pratt, Riccardo Amorati, Andrea Baschieri, Evan A. Haidasz, Derek Meng
Persistent dialkylnitroxides (e.g., 2,2,6,6-tetramethylpiperidin-1-oxyl, TEMPO) play a central role in the activity of hindered amine light stabilizers (HALS)-additives that inhibit the (photo)oxidative degradation of consumer and industrial products
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e58e60db40072843cb7968f5390cd6f1
http://hdl.handle.net/11585/542877
http://hdl.handle.net/11585/542877
Publikováno v:
Journal of the American Chemical Society. 134:12979-12988
High-level ab initio molecular orbital theory calculations are used to identify the origin of the remarkably high inhibition stoichiometric factors exhibited by dialkylamine-based radical-trapping antioxidants. We have calculated the free energy barr
Autor:
Keith U. Ingold, Gino A. DiLabio
Publikováno v:
Canadian Journal of Chemistry. 88:1053-1056
The g values that have been measured for the group-14 peroxyls are sufficiently similar to suggest that they all have very similar structures. However, the 17O hyperfine splittings seem to indicate that tin peroxyls have structures that differ from t
Publikováno v:
Angewandte Chemie. 130:9328-9328
Publikováno v:
Angewandte Chemie International Edition. 57:9186-9186
Publikováno v:
Angewandte Chemie. 121:163-166