Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Kedika Bal Reddy"'
Publikováno v:
Review of Scientific Instruments. 66:222-226
A high‐pressure optical cell has been designed that achieves an effective separation between the chemical sample and the pressurizing medium and system. This design limits possible sample contamination and catalytic effects under supercritical flui
Publikováno v:
Journal of Organometallic Chemistry. 440:113-117
A laser flash-photolysis study has been made of the pressure-dependence of a series of ring-closure reactions of the type Mo(CO)5LL → (CO)4Mo(L⌢L)+CO where LL represents 1,10-phenanthroline (phen) and a series of substituted phen ligands. T
Publikováno v:
Organometallics. 11:2319-2322
The kinetics of the ring-closure reactions of Mo(CO){sub 5}L, produced during the laser flash photolysis of Mo(CO){sub 6} and L where L = 2,2{prime}-bipyridine (bpy), 4,4{prime}-dimethyl-2,2{prime}-bipyridine (dpbpy) and 4,4{prime}-dephenyl-2,2{prime
Publikováno v:
Inorganica Chimica Acta. 175:83-89
Hydrolysis and racemization of Co(tmen)33+ (tmen=2,3-diamino-2,3-dimethylbutane) follow the rate law, rate = k[Co(tmen)33+][OH−] in the pH range 4.8 to 13.8. Kinetic parameters are k(hydr) = 2.5 ± 0.8 M−1 s−1 (298 K),ΔH*(hydr) = 1324 ± 3 kJ
Publikováno v:
Organometallics. 13:91-93
The kinetics of the thermal ring-closure reactions of W(CO)[sub 5]L, produced during the photolysis of W(CO)[sub 6]L, where L = 2,2'-bipyridine, 4,4'-dimethyl-2,2'-bipyridine, 4,4'-diphenyl-2,2'-bipyridine and 4,4'-di-tert-butyl-2,2'-bipyridine, were
Publikováno v:
Transition Metal Chemistry. 18:58-60
Oxidation of aryl β-styryl ketones by osmium tetroxide has been studied in H2SO4-HOAc medium. The order with respect to osmium is unity in all the cases and the [substrate] order is unity for aryl β-styryl ketone and fractional for substituted aryl
Autor:
Kedika Bal Reddy, R. Van Eldik
Publikováno v:
ChemInform. 21
Autor:
Qin Ji, Eyring, Edward M., van Eldik, Rudi, Reddy, Kedika Bal, Goates, Steven R., Lee, Milton L.
Publikováno v:
Review of Scientific Instruments; Jan1995, Vol. 66 Issue 1, p222, 5p, 4 Diagrams, 4 Graphs