Zobrazeno 1 - 10
of 73
pro vyhledávání: '"Kazutsugu Matsumoto"'
Autor:
K. Oohana, Kazutsugu Matsumoto, M. Hashimoto, Y. Suzuki, H. Ohshima, T. Togawa, K. Usuda, T. Shimoda
Publikováno v:
Tetrahedron. 74:3981-3988
We have succeeded in the easy preparation of optically active 1,2-diol monotosylates bearing an unsaturated substituent via enzymatic hydrolysis. Lipase PS quickly catalyzes the hydrolyses of 2-acetoxybut-3-enyl tosylate, which has a double bond, and
Publikováno v:
Journal of Biomaterials and Nanobiotechnology. :50-65
The enzyme-mediated highly enantioselective hydrolysis of aliphatic dicarboxylic acid diesters has been developed. The racemic diesters were easily prepared by the coupling of racemic alcohols with dicarboxylic anhydrides followed by esterification o
Publikováno v:
Journal of Molecular Catalysis B: Enzymatic. 109:94-100
We disclosed a useful procedure for the immobilization of a lipase from Burkholderia cepacia based on its encapsulation into vaterite calcium carbonate microcapsule. The immobilized enzyme had an adequate activity for the hydrolysis of 4-nitrophenyl
Publikováno v:
Tetrahedron: Asymmetry. 24:108-115
We have succeeded in accomplishing the deracemization of (±)-2-acetoxydecyl and (±)-acetoxy-6-benzyloxyhexyl tosylates, which have a long substituent, via an enzyme-mediated enantioselective hydrolysis with a Mitsunobu inversion using polymer-suppo
Publikováno v:
Letters in Organic Chemistry. 9:615-621
Publikováno v:
Letters in Organic Chemistry. 8:536-539
Autor:
Shota Asakura, Kazutsugu Matsumoto
Publikováno v:
Tetrahedron Letters. 55:6919-6921
We succeeded in the asymmetric nitroaldol (Henry) reaction of aromatic aldehydes with nitromethane using human serum albumin (HSA) in water at neutral pH. The reaction of 4-nitrobenzaldehyde smoothly proceeded for 24 h at 30 °C to afford the corresp
Autor:
Kanpei Ageishi, Tomomi Yamada, Takuya Nakagawa, Kazutsugu Matsumoto, Naoka Chihara, Katsumi Mizuochi, Masayuki Okudomi
Publikováno v:
Tetrahedron. 66:8060-8067
The enzyme-mediated enantioselective hydrolysis of water-soluble polymer-supported carboxylates is disclosed. The representative monomethoxy poly(ethylene glycol) (MPEG, av MW 5000)-supported substrate was synthesized by immobilization of (±)-1-phen
Autor:
Megumi Shimojo, Masayuki Okudomi, Masaki Nogawa, Takuya Nakagawa, Kazutsugu Matsumoto, Natsue Taketa, Ayae Hamanaka
Publikováno v:
Bulletin of the Chemical Society of Japan. 83:182-189
The enzyme-mediated enantioselective hydrolysis of middle molecular weight poly(ethylene glycol) (PEG)-supported carbonates is disclosed. The representative water-soluble substrate was prepared by ...
Publikováno v:
Tetrahedron: Asymmetry. 20:2802-2808
The deracemization of 1,2-diol monotosylate derivatives is achieved by the sequential combination of enzymatic hydrolysis and Mitsunobu inversion using a polymer-bound triphenylphosphine. After the lipase-catalysed hydrolysis of the racemic 2-acetoxy