Zobrazeno 1 - 3
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pro vyhledávání: '"Kazunari Yasumura"'
Publikováno v:
Proceedings of the National Academy of Sciences. 107:3994-3997
A [NiFe] hydrogenase model compound having a distorted trigonal-pyramidal nickel center, (CO) 3 Fe( μ -S t Bu) 3 Ni(SDmp), 1 (Dmp = C 6 H 3 -2,6-(mesityl) 2 ), was synthesized from the reaction of the tetranuclear Fe-Ni-Ni-Fe complex [(CO) 3 Fe( μ
Publikováno v:
Proceedings of the National Academy of Sciences of the United States of America. 107(9)
A [NiFe] hydrogenase model compound having a distorted trigonal-pyramidal nickel center, (CO)(3)Fe(micro-S(t)Bu)(3)Ni(SDmp), 1 (Dmp = C(6)H(3)-2,6-(mesityl)(2)), was synthesized from the reaction of the tetranuclear Fe-Ni-Ni-Fe complex [(CO)(3)Fe(mic
Autor:
Kazuyuki Tatsumi, Zilong Li, Kazunari Yasumura, Yasuhiro Ohki, Soichiro Tanino, Katsuaki Kuge, Masaru Ando
Publikováno v:
Proceedings of the National Academy of Sciences of the United States of America. 105(22)
The reaction of NiBr 2 (EtOH) 4 with a 1:2–3 mixture of FeBr 2 (CO) 4 and Na(SPh) generated a linear trinuclear Fe–Ni–Fe cluster (CO) 3 Fe(μ-SPh) 3 Ni(μ-SPh) 3 Fe(CO) 3 , 1, whereas the analogous reaction system FeBr 2 (CO) 4 /Na(S t Bu)/NiBr