Zobrazeno 1 - 10
of 35
pro vyhledávání: '"Kaveh Jorabchi"'
Publikováno v:
Analytical chemistry. 94(34)
Simultaneous elemental detection of F and Cl offers quantitation of fluorinated and chlorinated compounds and their transformation products without compound-specific standards. Despite wide-ranging applications, this capability has been hindered by f
Publikováno v:
Journal of Analytical Atomic Spectrometry. 37:870-882
Post-plasma chemical ionization of ICP-produced HF by barium-based reagent ions vastly improves F detection sensitivity compared to that of ICP-MS where ions are formed inside the plasma.
Autor:
Michael J. Dolan, Kaveh Jorabchi
Publikováno v:
Journal of Forensic Sciences. 66:1669-1678
Fluorinated polymer coatings are used to impart durable oil-and-water-repellent properties on fabrics, potentially offering a persistent fiber characteristic for forensic fiber comparisons. To evaluate the persistence of these coatings, we investigat
Autor:
Kaveh Jorabchi, Michael J. Dolan, Kunyu Zheng, Joseph E. Lesniewski, Tyler T. Metallo, Wanqing Li
Publikováno v:
Analytical Chemistry. 92:10129-10137
The growing use of fluorochemicals has elevated the need for nontargeted detection of unknown fluorinated compounds and transformation products. Elemental mass spectrometry (MS) coupled to chromatography offers a facile approach for such analyses by
Publikováno v:
Journal of the American Society for Mass Spectrometry. 31:488-497
We have previously shown that pulsed nano-ESI offers direct ion introduction into an AP-IM cell in the absence of conventional gates and desolvation. Here, we further characterize this ion injection method and utilize it to gain insights into nano-ES
Autor:
Kaveh Jorabchi, William P. McMahon
Publikováno v:
Analyst
Nano-ESI is a commonly used ionization technique with continually expanding analytical advantages. Here, we report a facile way for high-frequency (500–3800 Hz) pulsing of nano-ESI, providing a high flux of mobility-selected ions. The pulsing is ac
Publikováno v:
Analytical Chemistry. 91:3773-3777
Fluorine elemental analysis using inductively coupled plasma mass spectrometry (ICPMS) is challenging because of low F ionization efficiency in the plasma and severe isobaric interferences. Notably, there is an increasing demand for ppb level fluorin
Publikováno v:
Journal of Forensic Sciences.
Fluorinated coatings, often used for oil and water repellency and stain resistance in fabrics, are potentially persistent forensic fiber markers. However, they have received limited attention because of challenges in their detection caused by the sma
Publikováno v:
Analytical Chemistry. 90:2148-2154
Atmospheric-pressure dielectric barrier discharge (AP-DBD) plasma has emerged in recent years as a versatile plasma for molecular ionization and elemental spectroscopy. However, its capabilities as an elemental ion source have been less explored, par
Publikováno v:
Journal of Analytical Atomic Spectrometry. 33:1981-1992
Elemental analysis of chlorine using inductively coupled plasma mass spectrometry (ICP-MS) is challenging because of poor ion formation efficiency of Cl+ in the argon plasma, and prevalence of isobaric interferences. To improve Cl detection, we have