Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Katsuhiro Shimono"'
Publikováno v:
Chemistry - An Asian Journal. 4:1289-1297
Double Horner-Wadsworth-Emmons reaction of (E)-2,3-diaryl-1,4-bis(diethylphosphonyl)but-2-ene with (p-substituted) benzaldehydes gave (1E,3E,5E)-1,3,4,6-tetraarylhexa-1,3,5-trienes in moderate to good yields. Substitution of electron-withdrawing or -
Publikováno v:
Journal of Organometallic Chemistry. 686:286-293
gem-Silylborylation of halomethyllithiums with silylboranes allows us to prepare boryl(silyl)methanes substituted by such heteroatoms as Cl, Br, I, O, S, Si, Ge, and Sn in high yields. With B, Si, and Sn- or B, Ge, and Si-substituted methanes, the fi
Autor:
Shin-ichi Kiyomoto, Katsuhiro Shimono, Masaki Shimizu, Ikuhiro Nagao, Takuya Kurahashi, Tamejiro Hiyama
Publikováno v:
Bulletin of the Chemical Society of Japan. 81:518-520
Diels–Alder reaction of 2,3-bis(pinacolato)boryl-1,3-butadiene with electron-deficient alkenes and dimethyl acetylenedicarboxylate proceeded smoothly upon heating, giving rise to the corresponding ...
Publikováno v:
Synlett. 2007:1969-1971
The boryl group CIS to the C(3)=C(4) group in 2,4-aryl-1,1-bis(pinacolatoboryl)-1,3-butadienes undergoes Pd-catalyzed cross-coupling reaction with aryl iodides stereoselectively at room temperature, giving rise to the corresponding boronates as a sin
Autor:
Tamejiro Hiyama, Katsuhiro Shimono, Ikuhiro Nagao, Masaki Shimizu, Shin-ichi Kiyomoto, Takuya Kurahashi
Publikováno v:
ChemInform. 39
Diels–Alder reaction of 2,3-bis(pinacolato)boryl-1,3-butadiene with electron-deficient alkenes and dimethyl acetylenedicarboxylate proceeded smoothly upon heating, giving rise to the corresponding ...
Publikováno v:
ChemInform. 38
Treatment of (Z)-1,2,3,4-tetrakis(pinacolatoboryl)but-2-ene, prepared from 2,3-bis(pinacolatoboryl)buta-1,3-diene and bis(pinacolato)diboron, with three molar equivalents of aldehyde in toluene at 100 degrees C gave the 2,3-bis(alkylidene)alkane-1,5-
Autor:
Katsuhiro Shimono, Tamejiro Hiyama, Masaki Shimizu, Kei Tanaka, Takuya Kurahashi, Shin-ichi Kiyomoto, Ikuhiro Nagao
Publikováno v:
Chemistry, an Asian journal. 2(11)
Treatment of 1,1-bis(pinacolatoboryl)ethene with an excess of 1-bromo-1-lithioethene gave 2,3-bis(pinacolatoboryl)-1,3-butadiene in high yield. Palladium-catalyzed cross-coupling of the resulting diborylbutadiene with aryl iodides took place smoothly
Autor:
Michael Schelper, Katsuhiro Shimono, Takuya Kurahashi, Masaki Shimizu, Tamejiro Hiyama, Ikuhiro Nagao
Publikováno v:
ChemInform. 38
Cyclopropylidene lithium carbenoids reacted with bis(pinacolato)diboron in THF/Et2O at −110 °C to give various 1,1-diborylated cyclopropanes in good yields. Treatment of the diborylated cyclopropan...
Publikováno v:
ChemInform. 38
(Z)-l,2,3,4-Tetraboryl-2-butene reacted with three molecules of 2,3-dialkylidene-l,5-alkanediol as a single stereoisomer. Preparation and triple addition of the butene can be effected in a single operation.
Autor:
Katsuhiro Shimono, Masaki Shimizu, Michael Schelper, Tamejiro Hiyama, Chihiro Nakamaki, Takuya Kurahashi
Publikováno v:
Journal of the American Chemical Society. 127:12506-12507
Palladium-catalyzed cross-coupling reaction of 1,1-diboryl-1-alkenes with aryl and alkenyl iodides was found to proceed stereoselectively, giving rise to the corresponding mono-coupled product as a single diastereomer with E-configuration. Second cou