Výsledky vyhledávání - "Katrin Deller"

Synthesis and characterization of variously asymmetrically chloro-substituted disilanes and trisilanes – A new perspective on known compounds

Autor: Katrin Deller, Bernhard Rieger

Publikováno v: Journal of Organometallic Chemistry. 794:188-196

Asymmetrically phenyl-substituted disilanes of the general formula RMe 2 Si–SiMePh 2 ( MPD02 : R = Me, MPD12 : R = Ph) and the trisilane (PhMe 2 Si) 2 SiMePh ( MPT111 ) were prepared from the corresponding monosilanes using lithium as coupling reag

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7dfc3cbaeb5ea5c5eda20352de93e5ed
https://doi.org/10.1016/j.jorganchem.2015.06.035

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Synthesis of hydrocarbon-soluble, methyl-substituted highly branched polysilanes via the Wurtz-type reductive coupling of trifunctional trisilanes and their pyrolysis to silicon carbide

Autor: Bernhard Rieger, Katrin Deller

Publikováno v: RSC Advances. 5:87445-87455

A hydrocarbon-soluble, methyl-substituted highly branched polysilane was synthesized by subjecting a new type of monomer to the common Wurtz-type reductive coupling reaction conditions. For this purpose, the trichloro-substituted trisilane (ClMe2Si)2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f10605296b44343339be5a009517d9ac
https://doi.org/10.1039/c5ra19266h

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Metal-free polymerization of phenylsilane: tris(pentafluorophenyl)borane-catalyzed synthesis of branched polysilanes at elevated temperatures

Autor: Magnus R. Buchner, Alexander Genest, Sven U. H. Heidsieck, Katrin Deller, Andreas Feigl, Bernhard Rieger, Ion Chiorescu, Virve A. Karttunen, Andreas Bockholt, Notker Rösch

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 19(37)

The strong organoborane Lewis acid B(C6F5)3 catalyzes the polymerization of phenylsilane at elevated temperatures forming benzene and SiH4 as side-products. The resulting polymer is a branched polysilane with an irregular substitution pattern, as rev

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::04e51c2003f1f00ce181711679056785
https://pubmed.ncbi.nlm.nih.gov/23893573

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