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Publikováno v:
Learning & Behavior.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3b19cebfb72134dad79116ef151217b9
https://doi.org/10.3758/s13420-023-00573-5
https://doi.org/10.3758/s13420-023-00573-5
Publikováno v:
Organic Letters. 17:2614-2617
Boron-ate complexes derived from primary and secondary boronic esters and aryllithiums have been isolated, and the kinetics of their reactions with carbenium ions studied. The second-order rate constants have been used to derive nucleophilicity param
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f92fae75f6fe086ebc46d07f4133e13f
https://doi.org/10.1021/acs.orglett.5b00918
https://doi.org/10.1021/acs.orglett.5b00918
Publikováno v:
Plastic & Reconstructive Surgery; Apr1985, Vol. 75 Issue 4, p509-519, 11p
Autor:
Christopher Sandford, Guillaume Berionni, Varinder K. Aggarwal, Katie M J Feeney, Cristina García-Ruiz, Jack L.-Y. Chen, Paula Lorenzo, Herbert Mayr
Publikováno v:
García-Ruiz, C, Chen, J L Y, Sandford, C, Feeney, K M J, Lorenzo, P, Berionni, G, Mayr, H & Aggarwal, V K 2017, ' Stereospecific Allylic Functionalization : The Reactions of Allylboronate Complexes with Electrophiles ', Journal of the American Chemical Society, vol. 139, no. 43, pp. 15324-15327 . https://doi.org/10.1021/jacs.7b10240
Journal of the American Chemical Society
Journal of the American Chemical Society
Allylboronic esters react readily with carbonyls and imines (π-electrophiles), but are unreactive toward a range of other electrophiles. By addition of an aryllithium, the corresponding allylboronate complexes display enhanced nucleophilicity, enabl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cba86806881992c283b303c5d0fd8d13