Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Kathleen J. Muir"'
Publikováno v:
Crystals, Vol 1, Iss 2, Pp 47-58 (2011)
The syntheses and single-crystal structures of Mo(CO)3(phen)(dipy) (1), Mo(CO)3(biquin)(dipy) (2) and Mo(CO)3(dpme)(dipy) (3), (phen = 1,10-phenanthroline, C12H8N2; dipy = 2,2'-dipyridylamine, C10H9N3; biquin = 2,2'-biquinoline, C18H12N2; dpme = 2,2'
Externí odkaz:
https://doaj.org/article/37d2338ef3b74e1886431eadd989853a
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2918-m2918
The previous structure report [Howie & McQuillan (1986). J. Chem. Soc. Dalton Trans. pp. 759–764] of the title compound, [Mo(C10H8N2)(C10H9N3)(CO)3], has been corrected. In the present structure, the precision of the Mo—C and Mo—N bond distance
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2491-m2491
In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C—Mo—C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C—
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2493-m2493
In the title compound, [Mo(CO)3(C18H15P)(C10H8N2)] or C31H23MoN2O3P, the carbonyl groups are attached to one face of the MoC3N2P octahedron. In the crystal structure, a short C—H⋯O interaction (H⋯O = 2.41 A) may help to establish the packin
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2452-m2452
In the title compound, [Mo(C18H12N2)(CO)4], the differences in the Mo—C and C—O bond lengths may be interpreted in terms of a classical back-bonding model of electronic structure. In the crystal structure, an acute C—H⋯O interaction may h