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pro vyhledávání: '"Kate F. Donnelly"'
Autor:
Li-Xiong Shao, Rachelle Suen, Helge Müller-Bunz, Kate F. Donnelly, Martin Albrecht, Candela Segarra
Publikováno v:
Organometallics. 34:4076-4084
A ruthenium cymene complex bearing a bidentate ligand composed of the N-mesoionic donor N-[1-methylpyridin-4(1H)-ylidene]amide and the C-mesoionic donor 1,2,3-triazolylidene was prepared. Spectroscopic analyses including UV–vis, electrochemical, an
Autor:
Kate F. Donnelly, Martin Albrecht, Rainer Schobert, Tobias Rehm, Viktor Brabec, Vojtech Novohradsky, Jana Kasparkova, Thomas Mueller, Julienne K. Muenzner, Florian Schmitt
Publikováno v:
Journal of inorganic biochemistry. 163
Couples of N-heterocyclic carbene complexes of ruthenium, iridium, platinum, and gold, each differing only in the carbene ligand being either 1,3-dimethylimidazol-2-ylidene (IM) or 1,3-dimethyl-N-boc-O-methylhistidin-2-ylidene (HIS), were assessed fo
Publikováno v:
Organometallics
Organometallics, American Chemical Society, 2015, 34, pp.858-869. ⟨10.1021/om501197g⟩
Organometallics, American Chemical Society, 2015, 34, pp.858-869. ⟨10.1021/om501197g⟩
Iridium complexes containing a triazolylidene ligand with an appended methylpyridinium site undergo either aromatic C(sp2)–H bond activation or exocyclic C(sp3)–H bond activation of the N-bound methyl group. The selectivity of these bond activati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ee87f1ce78ddf6565079963fc3bfb6f7
https://hal.archives-ouvertes.fr/hal-01138729
https://hal.archives-ouvertes.fr/hal-01138729
Triazolylidenes have rapidly emerged as a powerful subclass of N-heterocyclic carbene ligands for transition metals. They are readily available through regioselective [2 + 3] cycloaddition of alkynes and azides and subsequent metallation according to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::700eedfdf5d704c2607dca229b9f3f04
Publikováno v:
Organometallics
Transmetalation of a 1,4-diphenyl-substituted 1,2,3-triazolylidene silver complex with an electrophilic metal center, e.g., RuII, IrIII, or RhIII, induces spontaneous and chemoselective cyclometalation involving C–H bond activation of the N-bound p