Zobrazeno 1 - 10
of 43
pro vyhledávání: '"Katalin Balázsik"'
Publikováno v:
Catalysis Communications. 32:81-85
The enantioselective hydrogenation of ketopantolactone (KPL) on Pt–alumina catalyst modified by β-isocinchonine (β-ICN) and O -phenylcinchonidine (PhOCD) in toluene, acetic acid and their mixtures under otherwise identical experimental conditions
Autor:
Katalin Balázsik, Ottó Berkesi, Gábor Szalontai, György Szőllősi, Ferenc Fülöp, Mihály Bartók
Publikováno v:
Topics in Catalysis. 55:880-888
The preparation and application of heterogeneous chiral catalysts are described. Heterogeneous Pd, Ir and Ru catalysts were tested in the enantioselective hydrogenations of N-heterocyclic compounds, namely 6,7-dimethoxy-3,4-dihydroisoquinoline and 1-
Publikováno v:
Catalysis Communications. 12:1410-1414
Competitive hydrogenations of eight binary mixtures of ethyl pyruvate (EP), methyl benzoylformate (MBF), ketopantolactone (KPL), pyruvic aldehyde dimethyl acetal (PA) and trifluoroacetophenone (TFAP) on platinum/alumina catalysts unmodified (racemic
Publikováno v:
Applied Catalysis A: General. 362:178-184
The enantioselective hydrogenation of 2,2,2-trifluoroacetophenone (TFAP) was investigated over Pt-cinchonidine (CD) and Pt-cinchona alkaloid derivatives chiral catalysts not yet studied in this reaction, such as Pt-cinchonine (CN), Pt-quinine (QN), P
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 305:155-160
The origin of rate enhancement in the enantioselective heterogeneous catalytic hydrogenation of ethyl pyruvate on Pt modified with the parent cinchonas, as compared to the unmodified Pt, was studied in a solvent mixture toluene/AcOH 9/1. Hydrogenatio
Autor:
Szabolcs Cserényi, Katalin Balázsik, György Szöllősi, Kornél Szőri, Imre Bucsi, Miklós Hollósi, Mihály Bartók, Elemér Vass, Károly Felföldi
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 294:14-19
Hydrogenation of α-ketoesters containing steroid groups at the ester side and at the keto carbonyl function of substrates was investigated the first time on Pt–alumina–cinchona alkaloids chiral catalysts using mild experimental conditions (room
Publikováno v:
Catalysis Letters. 125:401-407
The nonlinear phenomenon (NLP) was studied for the first time in the enantioselective hydrogenation of ethyl pyruvate (EP) and ketopantolactone (KPL) under identical conditions, on Pt catalyst modified by quinine and cinchonine, and for comparison wi
Publikováno v:
Catalysis Letters. 124:46-51
Results on nonlinear phenomenon (NLP) in the liquid phase hydrogenation of methyl benzoylformate (MBF) and pyruvaldehyde dimethyl acetal (PA) on chiral Pt-cinchona catalyst are reported for the first time (enantiomeric excess 90–95%). The new data
Autor:
Katalin Balázsik, Mihály Bartók, György Szöllősi, Tamás A. Martinek, Tibor Varga, Ferenc Fülöp
Publikováno v:
Journal of Catalysis. 255:296-303
Experimental evidence (measured by NMR) is given for the correlation between the solution-state concentration of the nucleophilic 1:1 modifier–substrate complex and the ee on enantioselective hydrogenation of ketopantolactone using Pt– β -isocin
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 285:84-91
The enantioselective hydrogenation of methyl benzoylformate (MBF) and pyruvaldehyde dimethyl acetal (PA) was investigated under mild experimental conditions on Pt-alumina catalyst modified with MeOCD, MeOCN, MeOQN and MeOQD alkaloid derivatives in ac