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Publikováno v:
Advanced Synthesis & Catalysis. 352:2281-2290
Conjugate additions of Gilman cyanocuprates to (S)-N-amino-2-(methoxymethyl)pyrrolidine (SAMP)-hydrazones 4, 5 derived from cyclic and acyclic α,β-unsaturated ketones were investigated. A protocol utilizing copper(II) sulfate/ammonium chloride was
Publikováno v:
ChemInform. 42
The method involves both the addition reaction and the cleavage of the hydrazone auxiliary under hydrolysis and work-up conditions by use of CuSO4/NH4Cl.