Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Karin Gruet"'
Autor:
Karin Gruet, Ben P. Patel, Alceo Macchioni, Odile Eisenstein, Robert H. Crabtree, Dong Heon Lee, Eric Clot
Publikováno v:
New Journal of Chemistry
New Journal of Chemistry, Royal Society of Chemistry, 2003, 27, pp.80-87. ⟨10.1039/b207339k⟩
New Journal of Chemistry, Royal Society of Chemistry, 2003, 27, pp.80-87. ⟨10.1039/b207339k⟩
International audience; A free pendant 2-amino group in a benzoquinolinate ligand bound to Ir(III) can cause heterolytic dissociation of an adjacent Ir-H-2, depending on the nature of the phosphine, L. For L=PMePh2, heterolysis does not occur and an
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d2b0268ee1b16795bb15d3c0f1fdf72b
https://doi.org/10.1039/b207339k
https://doi.org/10.1039/b207339k
Publikováno v:
Tetrahedron Letters. 41:7341-7345
The carbene–enolate complexes generated upon reaction of the carbene anion [Cp′(CO)2MnC(OEt)CH2]− with benzylidene acetone and chalcone react with benzaldehyde to form the 6-membered oxacyclocarbene complexes Cp′(CO)2MnCCH2CH(Ph)CH(C{O}
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0f40ffcb0dc1750a6267782e058ea32a
https://doi.org/10.1016/s0040-4039(00)01234-x
https://doi.org/10.1016/s0040-4039(00)01234-x
Autor:
Karin Gruet and, Arnold L. Rheingold, Louise M. Liable-Sands and, Robert H. Crabtree, Dong-Heon Lee
Publikováno v:
Organometallics. 19:2228-2232
An iridium complex having a 2-aminoquinolinate ligand can bind both lone pairs of ketones such as acetone and 2-hexanone in a two-point fashion via a coordinate Ir−O bond and an N−H···O hydrogen bond. This two-point binding orients the ketone
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2a00b2b54f972d2b397b62dda2122a21
https://doi.org/10.1021/om000115b
https://doi.org/10.1021/om000115b
Publikováno v:
Journal of Organometallic Chemistry. 600:7-11
In a biomimetic approach to organometallic catalysis, pendant hydrogen-bonding groups are shown to influence the chemistry of ligand binding and activation in an iridium complex. Such groups can bind a substrate by hydrogen bonding and so offer the p
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ceb076274165760b70794a2c9fba385d
https://doi.org/10.1016/s0022-328x(00)00030-9
https://doi.org/10.1016/s0022-328x(00)00030-9
Publikováno v:
Organometallics
Organometallics, American Chemical Society, 2001, 20, pp.2367-2373. ⟨10.1021/om010015l⟩
Organometallics, American Chemical Society, 2001, 20, pp.2367-2373. ⟨10.1021/om010015l⟩
International audience; NMR studies of the title compounds show that selective tight ion pairing occurs with the anion binding site being located in an intuitively unexpected region of the cation: on the side of the bipyridyl ligand remote from the m
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::adb06d2b6e3919293a80252bc10acd7d
https://hal.archives-ouvertes.fr/hal-00429104
https://hal.archives-ouvertes.fr/hal-00429104
Publikováno v:
ChemInform. 31
The carbene–enolate complexes generated upon reaction of the carbene anion [Cp′(CO)2MnC(OEt)CH2]− with benzylidene acetone and chalcone react with benzaldehyde to form the 6-membered oxacyclocarbene complexes Cp′(CO)2MnCCH2CH(Ph)CH(C{O}
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b1088b51ba6ba38a6f9248ba0bc6f525
https://doi.org/10.1002/chin.200050063
https://doi.org/10.1002/chin.200050063