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The first metal complexes of bis(diisopropylamino)carbene: synthesis, structure and ligand properties

Autor: Peter Sirsch, Karin Denk, Wolfgang A. Herrmann

Publikováno v: Journal of Organometallic Chemistry. 649:219-224

The synthesis of rhodium(I) and iridium(I) complexes of the bis(diisopropylamino)carbene is described for the first time. The formamidinium chloride and the free bis(diisopropylamino)carbene (L) were used as consecutive precursor compounds to form th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9d1d50f39a9208b18a08bcfae63bc866
https://doi.org/10.1016/s0022-328x(02)01133-6

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Tailoring of Catalysts: N-Heterocyclic Carbenes as an Example of Catalyst Design

Autor: Christian W. K. Gstoettmayr, Wolfgang A. Herrmann, Karin Denk

Publikováno v: ChemInform. 34

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d19758f1151f2e6294d747850660d46e
https://doi.org/10.1002/chin.200314261

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N-Heterocyclic Carbenes, Part 33.[1] Combining Stable NHC and Chelating Pyridinyl-Alcoholato Ligands: A Ruthenium Catalyst for Applications at Elevated Temperatures

Autor: Karin Denk, Jörg Fridgen, Wolfgang A. Herrmann

Publikováno v: Advanced Synthesis & Catalysis. 344:666

Ruthenium alkylidene complexes bearing one NHC ligand and one chelating pyridinyl alcoholate ligand 6 are generated by exchange of a phosphine ligand. Two synthetic approaches are presented: reacting the NHC phosphine complex 5 with the chelating lig

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::874da7e62d073e237ebeb05500561b72
https://doi.org/10.1002/1615-4169(200208)344:6/7<666::aid-adsc666>3.0.co

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Ruthenium Alkylidenes: Modulation of a New Class of Catalysts for Controlled Radical Polymerization of Vinyl Monomers

Autor: François Simal, Alfred F. Noels, Thomas Weskamp, Florian J. Kohl, Sébastien Delfosse, Karin Denk, Wolfgang A. Herrmann, Albert Demonceau

Publikováno v: Chemistry - A European Journal. 8:3047

Air-stable and readily available ruthenium benzylidene complexes of the general type [RuCl2(=CHPh)(L)(L')] (L, L' = PCy3 and/or N-heterocyclic carbene) constitute a new class of catalyst precursors for atom-transfer radical polymerization (ATRP) of m

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6baf3a282f41525aa0d8d8d2b811fef8
https://doi.org/10.1002/1521-3765(20020703)8:13<3047::aid-chem3047>3.0.co

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