Insights into the Scholl Coupling Reaction: A Key Transformation of Relevance to the Synthesis of Graphenes and Related Systems

Autor: Adam V. S. Parry, Mark Little, Alyn C. Edwards, James Raftery, Peter Quayle, Kane W. J. Heard, Aula A Alwattar, Stephen G. Yeates

Publikováno v: European Journal of Organic Chemistry. 2017:1694-1703

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7135f43d16c8a0518f99afac373cff90
https://doi.org/10.1002/ejoc.201601580

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Enhancement of CO2 Affinity in a Polymer of Intrinsic Microporosity by Amine Modification

Autor: Johannes C. Jansen, Peter M. Budd, Marek Lanč, Karel Friess, Kane W. J. Heard, Gabriele Clarizia, Louise Maynard-Atem, Bekir Satilmis, Paola Bernardo, Christopher R. Mason

Publikováno v: Macromolecules
47 (2014): 1021–1029. doi:10.1021/ma401869p
info:cnr-pdr/source/autori:Mason, Christopher R.; Maynard-Atem, Louise; Heard, Kane W J; Satilmis, Bekir; Budd, Peter M.; Friess, Karel; Lanc, Marek; Bernardo, Paola; Clarizia, Gabriele; Jansen, Johannes Carolus/titolo:Enhancement of CO2 affinity in a polymer of intrinsic microporosity by amine modification/doi:10.1021%2Fma401869p/rivista:Macromolecules (Print)/anno:2014/pagina_da:1021/pagina_a:1029/intervallo_pagine:1021–1029/volume:47

Nitrile groups in the polymer of intrinsic microporosity PIM-1 were reduced to primary amines using borane complexes. In adsorption experiments, the novel amine–PIM-1 showed higher CO2 uptake and higher CO2/N2 sorption selectivity than the parent p

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0520a3830c2852d02f5303a06abb873c
https://doi.org/10.1021/ma401869p

ChemInform Abstract: An Orthogonal C-H Borylation - Cross-Coupling Strategy for the Preparation of Tetrasubstituted 'A2B2'-Chrysene Derivatives with Tuneable Photophysical Properties

Autor: Laura Weston, C. H. Lo, John J. Morrison, Stephen G. Yeates, Lucian Pirvu, Peter Quayle, James Raftery, Kane W. J. Heard, Joseph J. W. McDouall, Mark Little

Publikováno v: ChemInform. 46

The title compounds are synthesized starting from 4,10-dichlorochrysene (I) by C—H borylation followed by substitution of firstly 2,8-positions affording derivatives (V) and secondly 4,10-positions (VII).

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::24f71b20c23f10309233246a62ecd320
https://doi.org/10.1002/chin.201531136

An orthogonal C-H borylation - cross-coupling strategy for the preparation of tetrasubstituted 'A(2)B(2)'-chrysene derivatives with tuneable photophysical properties

Autor: James Raftery, Lucian Pirvu, Kane W. J. Heard, Laura Weston, John J. Morrison, C. H. Lo, Peter Quayle, Stephen G. Yeates, Mark Little, Joseph J. W. McDouall

Publikováno v: Heard, K W J, Morrison, J, Weston, L, Lo, C H, Pirvu, L, Raftery, J, Little, M S, Mcdouall, J, Yeates, S G & Quayle, P 2015, ' An orthogonal C-H borylation-cross-coupling strategy for the preparation of tetrasubstituted "A(2)B(2)''-chrysene derivatives with tuneable photophysical properties ', Chemical Communications, vol. 51, no. 28, pp. 6115-6118 . https://doi.org/10.1039/c4cc10132d

The regioselective, orthogonal functionalisation of 4,10-dichlorochrysene enables the synthesis of a variety of 2,8,4,10-''A(2)B(2)''-tetrasubstituted chrysenes. Such compounds exhibit broadened UV-vis absorption spectra, decreased band gap and highe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ef7b1ac88b78a0f6bcc698882e249f37
https://www.research.manchester.ac.uk/portal/en/publications/an-orthogonal-ch-borylation--crosscoupling-strategy-for-the-preparation-of-tetrasubstituted-a2b2chrysene-derivatives-with-tuneable-photophysical-properties(879e5e91-1f5c-4dc5-b4e1-00fcc5b46ccd).html