High pressure synthesis of phosphine from the elements and the discovery of the missing (PH3)2H2 tile

Autor: Matteo Ceppatelli, Demetrio Scelta, Manuel Serrano-Ruiz, Kamil Dziubek, Gaston Garbarino, Jeroen Jacobs, Mohamed Mezouar, Roberto Bini, Maurizio Peruzzini

Publikováno v: Nature Communications, Vol 11, Iss 1, Pp 1-11 (2020)

Chemical elements at high pressure may behave more consistently with their periodic properties than they do at ambient conditions. The authors report the synthesis of PH3 from black phosphorous and hydrogen, and the crystallization of the van der Waa

Externí odkaz: https://doaj.org/article/279201f025c94439a590203efb6604bf

Insertion of Oxygen and Nitrogen in the Siliceous Zeolite TON at High Pressure

Autor: Marta Morana, Kamil Dziubek, Mario Santoro, Roberto Bini, Gaston Garbarino, Demetrio Scelta, Federico A. Gorelli, Julien Haines, Francesco Di Renzo, Arie van der Lee, Jérôme Rouquette, Benoit Coasne

Publikováno v: Journal of physical chemistry. C. (Online) 125 (2021): 19517–19524. doi:10.1021/acs.jpcc.1c05083
info:cnr-pdr/source/autori:Santoro M.; Morana M.; Scelta D.; Rouquette J.; Dziubek K.; Gorelli F.A.; Bini R.; Garbarino G.; Van Der Lee A.; Di Renzo F.; Coasne B.; Haines J./titolo:Insertion of Oxygen and Nitrogen in the Siliceous Zeolite TON at High Pressure/doi:10.1021%2Facs.jpcc.1c05083/rivista:Journal of physical chemistry. C. (Online)/anno:2021/pagina_da:19517/pagina_a:19524/intervallo_pagine:19517–19524/volume:125
Journal of Physical Chemistry C
Journal of Physical Chemistry C, American Chemical Society, 2021, 125 (35), pp.19517-19524. ⟨10.1021/acs.jpcc.1c05083⟩

The insertion of oxygen and nitrogen molecules in the one-dimensional (1D) pore system of the zeolite TON was studied at high pressure by vibrational spectroscopy, X-ray diffraction, and Monte Carlo (MC) molecular modeling. Rietveld refinements and M

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7863517f8ff796f43e3f3ffd0c762c5e
http://www.cnr.it/prodotto/i/456734

Extending the Stability Field of Polymeric Carbon Dioxide Phase V beyond the Earth's Geotherm

Autor: Roberto Bini, Gaston Garbarino, Ronald Miletich, Demetrio Scelta, Mohamed Mezouar, Martin Ende, Kamil Dziubek

Publikováno v: Physical review letters
126 (2021). doi:10.1103/PhysRevLett.126.065701
info:cnr-pdr/source/autori:Scelta D.; Dziubek K.F.; Ende M.; Miletich R.; Mezouar M.; Garbarino G.; Bini R./titolo:Extending the Stability Field of Polymeric Carbon Dioxide Phase v beyond the Earth's Geotherm/doi:10.1103%2FPhysRevLett.126.065701/rivista:Physical review letters (Print)/anno:2021/pagina_da:/pagina_a:/intervallo_pagine:/volume:126

We present a study on the phase stability of dense carbon dioxide (${\mathrm{CO}}_{2}$) at extreme pressure-temperature conditions, up to 6200 K within the pressure range $37\ifmmode\pm\else\textpm\fi{}9$ to $106\ifmmode\pm\else\textpm\fi{}17\text{ }

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::187148e915d0e3867cd8d8196b9e63e2
https://pubmed.ncbi.nlm.nih.gov/33635684

Pressure-Induced Polymerization of Polycyclic Arene-Perfluoroarene Cocrystals: Single Crystal X-ray Diffraction Studies, Reaction Kinetics, and Design of Columnar Hydrofluorocarbons

Autor: Roberto Bini, Javier Ruiz-Fuertes, Ines E. Collings, Kamil Dziubek, Todd B. Marder, Daniel Sieh, Samuele Fanetti, Krzysztof Radacki, Stewart J. Clark, Julio Pellicer-Porres, Michael Hanfland, Alexandra Friedrich

Publikováno v: Journal of the American Chemical Society (Online) 142 (2020): 18907–18923. doi:10.1021/jacs.0c09021
info:cnr-pdr/source/autori:Friedrich A.; Collings I.E.; Dziubek K.F.; Fanetti S.; Radacki K.; Ruiz-Fuertes J.; Pellicer-Porres J.; Hanfland M.; Sieh D.; Bini R.; Clark S.J.; Marder T.B./titolo:Pressure-Induced Polymerization of Polycyclic Arene-Perfluoroarene Cocrystals: Single Crystal X-ray Diffraction Studies, Reaction Kinetics, and Design of Columnar Hydrofluorocarbons/doi:10.1021%2Fjacs.0c09021/rivista:Journal of the American Chemical Society (Online)/anno:2020/pagina_da:18907/pagina_a:18923/intervallo_pagine:18907–18923/volume:142
Journal of the American Chemical Society, 2020, Vol.142(44), pp.18907-18923 [Peer Reviewed Journal]

Pressure-induced polymerization of aromatic compounds leads to novel materials containing sp3 carbon-bonded networks. The choice of the molecular species and the control of their arrangement in the crystal structures via intermolecular interactions,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1f5b1b3a94f699fd4546178cfa96d98
http://www.scopus.com/inward/record.url?eid=2-s2.0-85095667963&partnerID=q2rCbXpz

Dense, Subnano Phase of Clustered O 2

Autor: Kamil Dziubek, Jérôme Rouquette, Francesco Di Renzo, Julien Haines, Michael Hanfland, Roberto Bini, Mario Santoro, Marta Morana, Federico A. Gorelli, Demetrio Scelta

Publikováno v: Journal of Physical Chemistry C
Journal of Physical Chemistry C, American Chemical Society, 2019, 123 (14), pp.9651-9657. ⟨10.1021/acs.jpcc.9b02476⟩
Journal of physical chemistry. C 123 (2019): 9651–9657. doi:10.1021/acs.jpcc.9b02476
info:cnr-pdr/source/autori:Santoro M.; Dziubek K.; Scelta D.; Morana M.; Gorelli F.A.; Bini R.; Hanfland M.; Rouquette J.; Di Renzo F.; Haines J./titolo:Dense, Subnano Phase of Clustered O2/doi:10.1021%2Facs.jpcc.9b02476/rivista:Journal of physical chemistry. C/anno:2019/pagina_da:9651/pagina_a:9657/intervallo_pagine:9651–9657/volume:123

International audience; Condensed O2 tends to form clusters, even with a long-range order. In particular, in solid oxygen, strong intermolecular charge transfer at high pressures leads to the formation of (O2)4 tetramers above 10 GPa, in the ε-O2 ph

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::38a8b3d1d56fb2150b982ad7a58876d1
https://hal.umontpellier.fr/hal-02128207