Zobrazeno 1 - 10
of 34
pro vyhledávání: '"Kai-Stephan Feichtner"'
Publikováno v:
Inorganics, Vol 4, Iss 4, p 40 (2016)
The synthesis of [H2C(PPh2=NSiMe3)(SO2Ph)] (1) and its mono- and dimetalation are reported. Due to the strong anion-stabilizing abilities of the iminophosphoryl and the sulfonyl group monometalation to 1-K and dimetalation to 1-Li2 proceed smoothly w
Externí odkaz:
https://doaj.org/article/16a4c839887141e39eac500a3a8bd5a4
Autor:
Svenja Jäger, Philipp Meyer, Kai-Stephan Feichtner, Stefan Henkel, Gerhard W. Schwaab, Viktoria H. Gessner, Martina Havenith
Publikováno v:
Physical Chemistry Chemical Physics. 24:24089-24094
Alkali metal amides are highly reactive reagents that are broadly applied as strong bases in organic synthesis. Here, we use a combined helium nanodroplet IR spectroscopic and theoretical (DFT calculation) study to show that the reaction of the model
Autor:
Thorsten Scherpf, Nils Boysen, Bert Mallick, Lennart T. Scharf, Kai-Stephan Feichtner, Viktoria H. Gessner
Publikováno v:
Chemistry – A European Journal. 27:17351-17360
The use of iminophosphoryl-tethered ruthenium carbene complexes for activation of secondary phosphine P-H bonds is reported. Complexes of type [(p-cymene)-RuC(SO 2 Ph)(PPh 2 NR)] (with R = SiMe 3 or 4-C 6 H 4 -NO 2 ) were found to exhibit different r
Autor:
Ilja Rodstein, Jana-Alina Zur, Richard Gauld, Kai-Stephan Feichtner, Julian Löffler, Jens Handelmann, Christopher Schwarz, Viktoria H. Gessner
Publikováno v:
Organometallics
Ylide-substituted phosphines (YPhos) have been shown to be highly electron-rich and efficient ligands in a variety of palladium catalyzed transformations. Here, the synthesis and characterization of novel YPhos ligands containing a cyclic backbone ar
Autor:
Jana‐Alina Zur, Michelle Schmidt, Kai‐Stephan Feichtner, Prakash Duari, Julian Löffler, Thorsten Scherpf, Viktoria H. Gessner
Publikováno v:
Angewandte Chemie. 134
Although ylides are commonly used reagents in organic synthesis, the parent methylphosphine MePH
Autor:
Michelle Schmidt, Robert E. Mulvey, Angela Großjohann, Kai-Stephan Feichtner, Katharina Dilchert, Viktoria H. Gessner
Publikováno v:
Angewandte Chemie. 133:498-504
Autor:
Marina Saab, Nikolaos V. Tzouras, Kristof Van Hecke, Viktoria H. Däschlein-Gessner, Steven P. Nolan, Kai-Stephan Feichtner, Thorsten Scherpf, Heidar Darmandeh, Busra Dereli, Sofie M. P. Vanden Broeck, Julian Löffler, Catherine S. J. Cazin, Luigi Cavallo
Publikováno v:
Angewandte Chemie (International Ed. in English)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Secondary ligand–metal interactions are decisive in many catalytic transformations. While arene–gold interactions have repeatedly been reported as critical structural feature in many high‐performance gold catalysts, we herein report that these
Autor:
Kai-Stephan Feichtner, Viktoria H. Gessner, Lennart T. Scharf, Alexander B. Kowsari, Thorsten Scherpf
Publikováno v:
Organometallics. 38:4093-4104
A new PCcarbeneS ligand has been designed to stabilize late transition metal carbene complexes with Schrock-type reactivity for bond activations via metal–ligand cooperation. This ligand combines previous approaches to such complexes by stabilizing
Publikováno v:
European Journal of Inorganic Chemistry. 2019:2990-2995
Autor:
Christopher, Schwarz, Thorsten, Scherpf, Ilja, Rodstein, Julia, Weismann, Kai-Stephan, Feichtner, Viktoria H, Gessner
Publikováno v:
ChemistryOpen, Vol 8, Iss 5, Pp 621-626 (2019)
The α‐metallated ylides [Ph3P−C−Z]−M+ (with Z=SO2Tol or CN and M=Na or K) were used as versatile nucleophiles for the facile access to ylide‐substituted compounds. Halogenations, alkylations, carbonylations and functionalization reactions