Tandem Catalytic Amine Synthesis from Alkenes in Continuous Flow Enabled by Integrated Catalyst Recycling

Autor: Lasse Schurm, Kai U. Künnemann, Lisa Goclik, Dieter Vogt, Jonas Bianga, Thomas Seidensticker

Publikováno v: ACS Catalysis. 10:6463-6472

We present the development of catalytic auto-tandem reactions into continuous flow processes on the example of homogeneously catalyzed hydroaminomethylation (HAM, consisting of hydroformylation and...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bc4730ef392fcb159c57dfca3ca6c332
https://doi.org/10.1021/acscatal.0c01465

Process Development for the Rhodium-Catalyzed Reductive Amination in a Thermomorphic Multiphase System

Autor: Ricarda Scheel, Thomas Seidensticker, Kai U. Künnemann, Jens M. Dreimann, Jonas Bianga, Dieter Vogt

Publikováno v: Organic Process Research & Development. 24:41-49

For the first time, the successful application of the homogeneously catalyzed reductive amination in a thermomorphic multiphase system (TMS) and the first reported scale-up of this reaction into a ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e95858f0eee0b551416e47a025787828
https://doi.org/10.1021/acs.oprd.9b00409

Thermomorphic Multiphase Systems: Switchable Solvent Mixtures for the Recovery of Homogeneous Catalysts in Batch and Flow Processes

Autor: Jonas Bianga, Tom Gaide, Kai U. Künnemann, Andreas J. Vorholt, Dieter Vogt, Jens M. Dreimann, Thomas Seidensticker

Publikováno v: Chemistry – A European Journal. 25:11586-11608

Over the past 20 years, thermomorphic multiphase systems (TMS) have been used as a versatile and elegant strategy for the recovery and recycling of homogeneous transition-metal catalysts, in both batch-scale experiments and continuously operated proc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::94790933250a7399cda08284c2d080b9
https://doi.org/10.1002/chem.201902154

Aqueous Biphasic Hydroaminomethylation Enabled by Methylated Cyclodextrins: Sensitivity Analysis for Transfer into a Continuous Process

Autor: Chryslain Becquet, Kai U. Künnemann, Thomas Seidensticker, Sébastien Tilloy, Eric Monflier, Dennis Weber, Dieter Vogt

Publikováno v: ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering, 2021, ⟨10.1021/acssuschemeng.0c07125⟩
ACS Sustainable Chemistry & Engineering, American Chemical Society, 2021, ⟨10.1021/acssuschemeng.0c07125⟩

International audience; Hydroaminomethylation (HAM) is a highly efficient homogeneously catalyzed autotandem reaction converting alkenes into valuable amine products with water being the only coproduct. This work reports for the first time the scale-

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::88d0511914b2bf5a7ad9b357eb9f24d8
https://hal.science/hal-03107623

Identification of key mechanics in the ruthenium catalyzed synthesis of N,N-dimethylformamide from carbon dioxide in biphasic solvent systems

Autor: Manuel Nowotny, René Kuhlmann, Andreas J. Vorholt, Kai U. Künnemann, Arno Behr

Publikováno v: Journal of Catalysis. 361:45-50

The identification of crucial key factors in the homogenously catalyzed synthesis of N,N-dimethylformamide (DMF) from carbon dioxide with an integrated catalyst recycling is demonstrated in this work. All investigations were performed in a biphasic s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1cfc6a6f496f8943863caa5acd54d05c
https://doi.org/10.1016/j.jcat.2018.02.006