Zobrazeno 1 - 10 of 10 pro vyhledávání: '"Kai Oberdorf"'
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Insertion of CO2 and CS2 into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer
Autor: Kai Oberdorf, Anna Hanft, Xiulan Xie, F. Matthias Bickelhaupt, Jordi Poater, Crispin Lichtenberg
Publikováno v: Chemical Science, 14, 19, pp. 5214-5219
Chemical Science, 14, 5214-5219
The uptake and release of small molecules continue to be challenging tasks of utmost importance in synthetic chemistry. The combination of such small molecule activation with subsequent transformations to generate unusual reactivity patterns opens up
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f1baf1fedcefe220da6b03b5a63100e4
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5
Small molecule activation by well-defined compounds of heavy p-block elements
Autor: Kai Oberdorf, Crispin Lichtenberg
Publikováno v: Chemical Communications.
The creative design and exploration of new bonding motifs and molecular architectures in main group chemistry have pushed the boundaries of reactivity in this field of research. In this context,...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::68099660020de76d9aa4c13fd83da814
https://doi.org/10.1039/d3cc02190d
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7
CH Activation of Cationic Bismuth Amides: Heteroaromaticity, Derivatization, and Lewis Acidity
Autor: Crispin Lichtenberg, Kai Oberdorf, Jacqueline Ramler, Krzysztof Radacki, Patrick Grenzer, Anna Rempel, Anna Hanft, Nele Wieprecht, Andreas Stoy
Publikováno v: Inorganic chemistry. 60(24)
Cationization of Bi(NPh2)3 has recently been reported to allow access to single- and double-CH activation reactions, followed by selective transformation of Bi-C into C-X functional groups (X = electrophile). Here we show that this approach can succe
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1daeb8872ac646de01065a125f3cfe69
https://pubmed.ncbi.nlm.nih.gov/34818003
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8
Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn=N, P, As)
Autor: Jordi Poater, Ivo Krummenacher, Jacqueline Ramler, Anna Hanft, Kai Oberdorf, F. Matthias Bickelhaupt, Crispin Lichtenberg
Publikováno v: Oberdorf, K, Hanft, A, Ramler, J, Krummenacher, I, Bickelhaupt, F M, Poater, J & Lichtenberg, C 2021, ' Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn=N, P, As) ', Angewandte Chemie-International Edition, vol. 60, no. 12, pp. 6441-6445 . https://doi.org/10.1002/anie.202015514
Angewandte Chemie (International Ed. in English)
Angewandte Chemie. International Edition, 60, 12, pp. 6441-6445
Angewandte Chemie. International Edition, 60, 6441-6445
Angewandte Chemie International Edition
Angewandte Chemie-International Edition, 60(12), 6441-6445. Wiley
The controlled release of well‐defined radical species under mild conditions for subsequent use in selective reactions is an important and challenging task in synthetic chemistry. We show here that simple bismuth amide species [Bi(NAr2)3] readily r
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a50aa61805fb28c8b4083453ba376d3c
https://research.vu.nl/en/publications/b34aee70-0abe-400b-930b-9cf0d1b13030
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9
Toward Transition-Metal-Templated Construction of Arylated B
Autor: Carsten, Lenczyk, Dipak Kumar, Roy, Kai, Oberdorf, Jörn, Nitsch, Rian D, Dewhurst, Krzysztof, Radacki, Jean-François, Halet, Todd B, Marder, Matthias, Bickelhaupt, Holger, Braunschweig
Publikováno v: Chemistry (Weinheim an Der Bergstrasse, Germany)
The reactivity of a diruthenium tetrahydride complex towards three selected dihydroboranes was investigated. The use of [DurBH2] (Dur=2,3,5,6‐Me4C6H) and [(Me3Si)2NBH2] led to the formation of bridging borylene complexes of the form [(Cp*RuH)2BR] (
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::8ce7503802651c45b32a5fb4d80346d7
https://pubmed.ncbi.nlm.nih.gov/31663648
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10
Toward Transition-Metal-Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling
Autor: Krzysztof Radacki, Todd B. Marder, Jörn Nitsch, Carsten Lenczyk, Dipak Kumar Roy, Kai Oberdorf, Rian D. Dewhurst, F. Matthias Bickelhaupt, Holger Braunschweig, Jean-François Halet
Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2019, 25 (72), pp.16544-16549. ⟨10.1002/chem.201904772⟩
Lenczyk, C, Roy, D K, Oberdorf, K, Nitsch, J, Dewhurst, R D, Radacki, K, Halet, J F, Marder, T B, Bickelhaupt, M & Braunschweig, H 2019, ' Toward Transition-Metal-Templated Construction of Arylated B 4 Chains by Dihydroborane Dehydrocoupling ', Chemistry-A European Journal, vol. 25, no. 72, pp. 16544-16549 . https://doi.org/10.1002/chem.201904772
Chemistry-A European Journal, 25(72), 16544-16549. Wiley-VCH Verlag
Chemistry : a European Journal, 25, 72, pp. 16544-16549
Chemistry : a European Journal, 25, 16544-16549
Chemistry-A European Journal, 2019, 25 (72), pp.16544-16549. ⟨10.1002/chem.201904772⟩
The reactivity of a diruthenium tetrahydride complex towards three selected dihydroboranes was investigated. The use of [DurBH2] (Dur=2,3,5,6-Me4C6H) and [(Me3Si)2NBH2] led to the formation of bridging borylene complexes of the form [(Cp*RuH)2BR] (Cp
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a5f48dee06bc9ee6e7c8b4dfa2eaf28f
https://doi.org/10.1002/chem.201904772
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