Zobrazeno 1 - 10
of 24
pro vyhledávání: '"Kai Exner"'
Autor:
Kai Exner
Publikováno v:
Nachrichten aus der Chemie. 71:114-114
Autor:
Luis Arturo Ruiz-Preciado, Kai Exner, Uli Lemmer, Stefan Schlisske, Gerardo Hernandez-Sosa, Sebastian Raths
Publikováno v:
Flexible and printed electronics, 6, Article no: 015002
The applicability of inkjet-printed (opto-)electrical devices are hindered by their low lateral resolution, when compared to conventional techniques. The low lateral resolution is mainly caused by the flow and spreading of the functional ink on the s
Autor:
Thomas Musiol, Pascal Hayoz, Zhou Mi, Oriol Ossó, Roger Pretot, Jochen Brill, Daniel Kaelblein, Fulvio Giacomo Brunetti, Kai Exner, Daniel Bahl
Publikováno v:
SID Symposium Digest of Technical Papers. 47:869-871
Targeting flexible display backplanes and circuitry, BASF is developing high performance materials for Organic Field-Effect Transistors. Here we present our recent development focusing on directly photo-patternable semiconductors and dielectrics, as
Autor:
Fushun Yang, Kai Exner, Markus Kegel, Birgit Großmann, Horst Prinzbach, Markus Heizmann, Manfred Keller, Jürgen Heinze, Lothar Knothe
Publikováno v:
European Journal of Organic Chemistry. 2005:1311-1331
In the pursuit of novel bishomoconjugated (σ-bishomoaromatic) 4N/7(6)e bonding motifs, (bisseco)pagodane/isopagodane and dodecahedrane-like, caged, proximate-parallel bishydrazines have been designed as suitable host skeletons. The derived radical c
Publikováno v:
Angewandte Chemie. 117:2485-2490
Na4N8-Kuboktaeder mit nahezu planaren N4-Polygonen (siehe Struktur) bilden im Festkorper wie auch in Losung die Kerne der Dimerstrukturen bemerkenswert persistenter bishomoaromatischer Dianionen, die durch Reduktion von vororientierten Bisdiazenen mi
Autor:
Markus Vögtle, Fushun Yang, Horst Prinzbach, Lothar Knothe, Eberhard Beckmann, Oliver Cullmann, Manfred Keller, Markus Kegel, Kai Exner, Nicolaus Bahr
Publikováno v:
European Journal of Organic Chemistry. 2003:4248-4264
Synthetic details are presented for a series of more or less rigid, “parallel-in-plane” preoriented bis(diazenes), with N=N/N=N distances (d) of 3.3−2.9 A and interorbital angles (ψ) of 142−164° (X-ray crystal structures). DFT calculations
Autor:
Dieter Hunkler, Kai Exner, Fushun Yang, Oliver Cullmann, Markus Kegel, Horst Prinzbach, Markus Vögtle, Jens Geier
Publikováno v:
Tetrahedron. 58:1137-1145
By oxidation of (presumably) bislithiated, unusually proximate, syn-periplanar bishydrazines an alternative access to σ-bishomoaromatic 4N/6e dianions is realized. Formal N-alkylation/arylation of these 4N/6e dianions leads to novel, cyclically delo
Autor:
Paul von Ragué Schleyer, Kai Exner and
Publikováno v:
The Journal of Physical Chemistry A. 105:3407-3416
The recently proposed scheme of Grimme (BE scheme) (J. Am. Chem. Soc. 1996, 118, 1529) to calculate intrinsic bond energies (BE's) of hydrocarbons, which define seminal equilibrium quantities of chemical structures, is evaluated critically. CH and re
Autor:
Kai Exner, Paul von Ragué Schleyer
Publikováno v:
Science. 290:1937-1940
The viability of molecules with planar hexacoordinate carbon atoms is demonstrated by density-functional theory (DFT) calculations for CB 6 2– , a CB 6 H 2 isomer, and three C 3 B 4 minima. All of these species have six π electrons and are aromati
Autor:
Birgit Großmann, Georg Gescheidt, Horst Prinzbach, Jürgen Heinze, Kai Exner, Pavel Bednarek, Thomas Bally
Publikováno v:
Tetrahedron Letters. 41:9595-9600
One- and two-electron oxidation of a caged, proximate, syn -periplanar bishydrazine leads to highly persistent, 4N/(7)6e (radical) cations—with dominant electron delocalisation along the cage bonds (CV, EPR, B3LYP). A NICS value of −20.6 is evide