Simultaneous Detection of Circularly Polarized Luminescence and Raman Optical Activity in an Organic Molecular Lemniscate

Autor: Luis Palomo, Ludovic Favereau, Kabali Senthilkumar, Marcin Stępień, Juan Casado, Francisco J. Ramírez

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2022, 61 (34), pp.-e202206976. ⟨10.1002/anie.202206976⟩
RIUMA. Repositorio Institucional de la Universidad de Málaga
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Circularly polarized luminescence (CPL) and Raman optical activity (ROA) were observed in a single spectroscopic experiment for a purely organic molecule, an event that had so far been limited to lanthanide-based complexes. The present observation wa

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4227e77d39d602d712fed8b630c7ef6a
https://hal.science/hal-03772724

Synthesis and characterization of d10 metal complexes of 3-Me-5-FcPz: Structural, theoretical and third order nonlinear optical properties

Autor: Kabali Senthilkumar, Nattamai Bhuvanesh, Nallasamy Palanisami, Kiran Soni, G. Vinitha, Krishnan Thirumoorthy

Publikováno v: Journal of Molecular Structure. 1128:36-43

The d10 metal complexes based on 3-methyl-5-ferrocenyl-1H-pyrazole (L = 3-Me-5-FcPz) ligand [M(L)4(NO3)2] Zn=(1) and Cd=(2), [Hg(L)4(NO3)2].dmf (3) have been synthesized and characterized by FT-IR, NMR, UV–Vis and elemental analysis. The molecular

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9055dd321a63d74c82d5c190432bd056
https://doi.org/10.1016/j.molstruc.2016.08.036

Monomeric zinc ferrocene carboxylate [Zn(FcCOO)(3,5-dmp)2Cl] derived from 3,5-dimethylpyrazole: structural, optical, electrochemical and antimicrobial studies

Autor: Swaminathan Shanmugan, Nallasamy Palanisami, Ezhumalai David, Gurudevaru Champaka, Kabali Senthilkumar

Publikováno v: Journal of Molecular Structure. 1228:129749

Monomeric zinc ferrocene carboxylate [Zn(FcCOO)(3,5-dmp)2Cl] (1) has been synthesized from a reaction between the zinc chloride, sodium salt of ferrocene carboxylic acid (FcCOONa) and 3,5-dimethylpyrazole (3,5-dmp) at room temperature. Compound 1 was

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::57d4932872ca25a0de39731e7e926383
https://doi.org/10.1016/j.molstruc.2020.129749

Ferrocene-quinoxaline Y-shaped chromophores as fascinating second-order NLO building blocks for long lasting highly active SHG polymeric films

Autor: Kabali Senthilkumar, Daniele Marinotto, Claudia Dragonetti, Matti Haukka, Krishnan Thirumoorthy, Stefania Righetto, Alessia Colombo, Nallasamy Palanisami

Publikováno v: Dalton transactions (2003. Print) 45 (2016): 11939–11943. doi:10.1039/c6dt01590e
info:cnr-pdr/source/autori:Senthilkumar, Kabali; Thirumoorthy, Krishnan; Dragonetti, Claudia; Marinotto, Daniele; Righetto, Stefania; Colombo, Alessia; Haukka, Matti; Palanisami, Nallasamy/titolo:Ferrocene-quinoxaline Y-shaped chromophores as fascinating second-order NLO building blocks for long lasting highly active SHG polymeric films/doi:10.1039%2Fc6dt01590e/rivista:Dalton transactions (2003. Print)/anno:2016/pagina_da:11939/pagina_a:11943/intervallo_pagine:11939–11943/volume:45

The first example of a Y-shaped ferrocene quinoxaline derivative with a surprisingly high and stable second harmonic generation (SHG) response in composite polymeric films is reported. The interesting quadratic hyperpolarizability values of different

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::69b2e8a14f30c1cbdb3fe8427ea948f7
https://doi.org/10.1039/c6dt01590e

Synthesis and structural and DNA binding studies of mono‐ and dinuclear copper(II) complexes constructed with ─O and ─N donor ligands: Potential anti‐skin cancer drugs

Autor: Champaka Gurudevaru, Nallasamy Palanisami, Kabali Senthilkumar, Devadasan Velmurugan, Swaminathan Shanmugan, Hridya Hemachandran, Thothadri Srinivasan, Mohan Gopalakrishnan, Ramamoorthy Siva

Publikováno v: Applied Organometallic Chemistry. 32

Mononuclear and dinuclear copper(II) complexes with thiophenecarboxylic acid, [Cu(3-TCA)2(2,2′-bpy)] (1), [Cu(3-Me-2-TCA)2(H2O)(2,2′-bpy)] (2), [Cu(5-Me-2-TCA)2(H2O)(2,2′-bpy)] (3) and [Cu2(2,5-TDCA)(DMF)2(H2O)2(2,2′-bpy)2](ClO4)2 (4) (where

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::da3483d0bfe6f01364e60475d67edb77
https://doi.org/10.1002/aoc.3998