Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Ka Hou Hoi"'
Publikováno v:
Angewandte Chemie International Edition. 51:3314-3332
Palladium-catalyzed cross-coupling reactions enable organic chemists to form C-C bonds in targeted positions and under mild conditions. Although phosphine ligands have been intensively researched, in the search for even better cross-coupling catalyst
Die Entwicklung raumerfüllender Palladium-NHC-Komplexe für anspruchsvollste Kreuzkupplungsreaktionen
Publikováno v:
Angewandte Chemie. 124:3370-3388
Palladiumkatalysierte Kreuzkupplungen versetzten Organiker in die Lage, C-C-Bindungen gezielt und unter milden Reaktionsbedingungen zu einzufuhren. Wahrend Phosphanliganden in diesen Umsetzungen am intensivsten erforscht wurden, sind seit kurzem auf
Autor:
Michael G. Organ, Ka Hou Hoi
Publikováno v:
Chemistry - A European Journal. 18:804-807
This base is just right! A new base, potassium 2,2,5,7,8-pentamethylchroman-6-oxide, for Pd-catalysed amination has been rationally designed that has sufficient basicity to efficiently deprotonate the intermediate aryl palladium ammonium complex, lea
Publikováno v:
Chemistry - A European Journal. 18:145-151
The amination of aryl chlorides with various aniline derivatives using the N-heterocyclic carbene-based Pd complexes Pd-PEPPSI-IPr and Pd-PEPPSI-IPent (PEPPSI=pyridine, enhanced precatalyst, preparation, stabilization, and initiation; IPr=diisopropyl
Publikováno v:
Chemistry – A European Journal. 17:3086-3090
Pd-PEPPSI-IPent, a recently-developed N-heterocyclic carbene (NHC) complex, has been evaluated in amination reactions with secondary amines and it has shown superb reactivity under the most mildly basic reaction conditions. Rate and computational stu
Publikováno v:
Chemistry - A European Journal. 19:843-845
Third times a charm: A new Pd-NHC catalyst, Pd-PEPPSI-IPent(Cl), has been developed for applications in amination reactions for the preparation of triarylamines. The catalyst can be used under mild conditions (carbonate base/dioxane, 80 °C) to perfo
Publikováno v:
ChemInform. 44
Third times a charm: A new Pd-NHC catalyst, Pd-PEPPSI-IPent(Cl), has been developed for applications in amination reactions for the preparation of triarylamines. The catalyst can be used under mild conditions (carbonate base/dioxane, 80 °C) to perfo
Publikováno v:
ChemInform. 43
Palladium-catalyzed cross-coupling reactions enable organic chemists to form C-C bonds in targeted positions and under mild conditions. Although phosphine ligands have been intensively researched, in the search for even better cross-coupling catalyst
Publikováno v:
ChemInform. 40
Incredible Bulk: A series of N-heterocyclic carbene catalysts (see picture) were prepared and evaluated in the Suzuki-Miyaura reaction. A variety of sterically encumbered tetra-ortho-substituted biaryl products were formed from unreactive aryl chlori
Publikováno v:
Angewandte Chemie (International ed. in English). 48(13)
Incredible Bulk: A series of N-heterocyclic carbene catalysts (see picture) were prepared and evaluated in the Suzuki-Miyaura reaction. A variety of sterically encumbered tetra-ortho-substituted biaryl products were formed from unreactive aryl chlori